Bright zinc electrodeposition and study of influence of synergistic interaction of additives on coating properties

K.O. Nayana; T.V. Venkatesha

Journal of Industrial and Engineering Chemistry, Vol.26, 107-115, June, 2015

DOI10.1016/j.jiec.2014.11.021 Export Citation

Bright zinc electrodeposition and study of influence of synergistic interaction of additives on coating properties

K.O. Nayana, and T.V. Venkatesha^†

Department of PG Studies & Research in Chemistry, Kuvempu University, Shankaraghatta 577 451, India

E-mail:

The nanocrystalline, bright zinc coating was produced using additives, cetyltrimethylammonium bromide (CTAB) and condensation product of valine and veratraldehyde (VV). The synergistic influence of VV + CTAB and simultaneously effect of VV content in bath on surface morphology, texture and grain size of zinc electrodeposits were systematically analyzed. In addition, effect of additives on efficiency, throwing power and deposit properties like microhardness, reflectance and corrosion resistance was investigated. The study reveals that morphological and structural changes observed in presence of additives exhibits synergistic influence on improving corrosion resistance and hardness of the deposit.

Keywords:Electroplating;Brightener;Morphological;Microhardness;Synergestic effect;Corrosion resistance

[References]

Wilcox GD, Gabe DR, Corrosion Sci., 35, 1251 (1993)
Parthasaradhy NV, Practical Electroplating Handbook, first ed., Prentice Hall Inc., New Jersey, 1989p. 1.
Nayana KO, Venkatesha TV, Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 40, 170 (2010)
Naik YA, Venkatesh TV, Ind. J. Eng. Mater. Sci., 40, 318 (2003)
Naik YA, Venkatesha TV, Nayak PV, Indian J. Chem. Technol., 8(5), 390 (2001)
Ortiz-Aparicio JL, Meas Y, Trejo G, Ortega R, Chapman TW, Chainet E, J. Appl. Electrochem., 43(3), 289 (2013)
Kavitha B, Santhosh P, Renukadevi M, Kapanam A, Shakkthivel P, Vasudevan T, Surf. Coat. Technol., 201, 3438 (2006)
Boto K, Electrodepos. Surf. Treat., 3, 77 (1975)
Shanmugasigamani, Pushpavanam M, J. Appl. Electrochem., 36(3), 315 (2006)
Kim SJ, Kim HT, Park SM, J. Electrochem. Soc., 151(12), C850 (2004)
Li MC, Luo SZ, Qian YH, Zhang WQ, Jiang LL, Shen JN, J. Electrochem. Soc., 154(11), D567 (2007)
Achary G, Sachin HP, Naik YA, Venkatesh TV, Bull. Mater. Sci., 30, 219 (2007)
Chandrasekar MS, Shanmugasigamani, Pushpavanam M, Mater. Chem. Phys., 124(1), 516 (2010)
Zhang QB, Hua YX, Dong TG, Zhou DG, J. Appl. Electrochem., 39, 1207 (2007)
Moron LE, Mendez A, Castaneda F, Flores JG, Ortiz-Frade L, Meas Y, Trejo G, Surf. Coat. Technol., 205, 4985 (2011)
Muralidhara HB, Naik YA, Bull. Mat. Sci., 31, 585 (2008)
Hsieh JC, Hu CC, Lee TC, J. Electrochem. Soc., 155(10), D675 (2008)
Mouanga M, Ricq L, Douglade J, Bercot P, J. Appl. Electrochem., 37(2), 283 (2007)
Loto A, Res. Chem. Intermed., 40, 1799 (2014)
Loto CA, Loto RT, Int. J. Electrochem. Sci., 8, 12434 (2013)
Cullity BD, Elements of X-ray Diffraction, second ed., Addision-Wesley Publishing Company, Inc., Philippines, 1978.
Muresan L, Oniciu L, Froment M, Maurin G, Electrochim. Acta, 37, 2249 (1992)
Kim SH, Sohn HJ, Joo YC, Kim YW, Yim TH, Lee HY, Kang T, Surf. Coat. Technol., 199, 43 (2005)
Ramanauskas R, Quintana P, Maldonado L, Pomes R, Pech-Canul MA, Surf. Coat. Technol., 92, 16 (1997)
ASTM D523-89, 2001 Standard Test Method for Specular Gloss, 6, 1999, p. 35.
Matysina ZA, Chuprina LM, Zaginoichenko YS, J. Phys. Chem. Solids, 53, 167 (1992)
Gomes A, Pereira MID, Electrochim. Acta, 51(7), 1342 (2006)
Saber K, Koch CC, Fedkiw PS, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 341, 174 (2003)
Honeycombe RWK, The Plastic Deformation of Metal, second ed., Edward Arnold, London, 1984.
Nayana KO, Venkatesha TV, Chandrappa KG, Surf. Coat. Technol., 235, 461 (2013)
Mei Z, Morris JW, in: Marder AR (Ed.), The Physical Metallurgy of Zinc Coating Steel, TMS, Warrendale, PA, 1994, p. 11.
Mouanga M, Ricq L, Douglade J, Bercot P, Corrosion Sci., 51, 690 (2009)
Qu Q, Li L, Bai W, Yan C, Cao CN, Corrosion Sci., 47, 2832 (2005)
Boshkov N, Surf. Coat. Technol., 172, 217 (2003)
Praveen BM, Venkatesha TV, J. Alloy. Compd., 482, 53 (2009)
Scully JC, in: Masson (Ed.), Corrosion Protection: Principes Fondamentaux, Masson, Paris, 1995.
Zhang XY, Shi MH, Li C, Liu NF, Wei YM, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 448, 259 (2007)
Park H, Szpunar JA, Corrosion Sci., 40, 525 (1998)
Vlasa A, Varvara S, Pop A, Bulea C, Muresan LM, J. Appl. Electrochem., 40(8), 1519 (2010)

[Referenced By]

[1] Wilcox GD, Gabe DR, Corrosion Sci., 35, 1251 (1993)

[2] Parthasaradhy NV, Practical Electroplating Handbook, first ed., Prentice Hall Inc., New Jersey, 1989p. 1.

[3] Nayana KO, Venkatesha TV, Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 40, 170 (2010)

[4] Naik YA, Venkatesh TV, Ind. J. Eng. Mater. Sci., 40, 318 (2003)

[5] Naik YA, Venkatesha TV, Nayak PV, Indian J. Chem. Technol., 8(5), 390 (2001)

[6] Ortiz-Aparicio JL, Meas Y, Trejo G, Ortega R, Chapman TW, Chainet E, J. Appl. Electrochem., 43(3), 289 (2013)

[7] Kavitha B, Santhosh P, Renukadevi M, Kapanam A, Shakkthivel P, Vasudevan T, Surf. Coat. Technol., 201, 3438 (2006)

[8] Boto K, Electrodepos. Surf. Treat., 3, 77 (1975)

[9] Shanmugasigamani, Pushpavanam M, J. Appl. Electrochem., 36(3), 315 (2006)

[10] Kim SJ, Kim HT, Park SM, J. Electrochem. Soc., 151(12), C850 (2004)

[11] Li MC, Luo SZ, Qian YH, Zhang WQ, Jiang LL, Shen JN, J. Electrochem. Soc., 154(11), D567 (2007)

[12] Achary G, Sachin HP, Naik YA, Venkatesh TV, Bull. Mater. Sci., 30, 219 (2007)

[13] Chandrasekar MS, Shanmugasigamani, Pushpavanam M, Mater. Chem. Phys., 124(1), 516 (2010)

[14] Zhang QB, Hua YX, Dong TG, Zhou DG, J. Appl. Electrochem., 39, 1207 (2007)

[15] Moron LE, Mendez A, Castaneda F, Flores JG, Ortiz-Frade L, Meas Y, Trejo G, Surf. Coat. Technol., 205, 4985 (2011)

[16] Muralidhara HB, Naik YA, Bull. Mat. Sci., 31, 585 (2008)

[17] Hsieh JC, Hu CC, Lee TC, J. Electrochem. Soc., 155(10), D675 (2008)

[18] Mouanga M, Ricq L, Douglade J, Bercot P, J. Appl. Electrochem., 37(2), 283 (2007)

[19] Loto A, Res. Chem. Intermed., 40, 1799 (2014)

[20] Loto CA, Loto RT, Int. J. Electrochem. Sci., 8, 12434 (2013)

[21] Cullity BD, Elements of X-ray Diffraction, second ed., Addision-Wesley Publishing Company, Inc., Philippines, 1978.

[22] Muresan L, Oniciu L, Froment M, Maurin G, Electrochim. Acta, 37, 2249 (1992)

[23] Kim SH, Sohn HJ, Joo YC, Kim YW, Yim TH, Lee HY, Kang T, Surf. Coat. Technol., 199, 43 (2005)

[24] Ramanauskas R, Quintana P, Maldonado L, Pomes R, Pech-Canul MA, Surf. Coat. Technol., 92, 16 (1997)

[25] ASTM D523-89, 2001 Standard Test Method for Specular Gloss, 6, 1999, p. 35.

[26] Matysina ZA, Chuprina LM, Zaginoichenko YS, J. Phys. Chem. Solids, 53, 167 (1992)

[27] Gomes A, Pereira MID, Electrochim. Acta, 51(7), 1342 (2006)

[28] Saber K, Koch CC, Fedkiw PS, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 341, 174 (2003)

[29] Honeycombe RWK, The Plastic Deformation of Metal, second ed., Edward Arnold, London, 1984.

[30] Nayana KO, Venkatesha TV, Chandrappa KG, Surf. Coat. Technol., 235, 461 (2013)

[31] Mei Z, Morris JW, in: Marder AR (Ed.), The Physical Metallurgy of Zinc Coating Steel, TMS, Warrendale, PA, 1994, p. 11.

[32] Mouanga M, Ricq L, Douglade J, Bercot P, Corrosion Sci., 51, 690 (2009)

[33] Qu Q, Li L, Bai W, Yan C, Cao CN, Corrosion Sci., 47, 2832 (2005)

[34] Boshkov N, Surf. Coat. Technol., 172, 217 (2003)

[35] Praveen BM, Venkatesha TV, J. Alloy. Compd., 482, 53 (2009)

[36] Scully JC, in: Masson (Ed.), Corrosion Protection: Principes Fondamentaux, Masson, Paris, 1995.

[37] Zhang XY, Shi MH, Li C, Liu NF, Wei YM, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 448, 259 (2007)

[38] Park H, Szpunar JA, Corrosion Sci., 40, 525 (1998)

[39] Vlasa A, Varvara S, Pop A, Bulea C, Muresan LM, J. Appl. Electrochem., 40(8), 1519 (2010)