Adsorption and energetic heterogeneity properties of cesium ions on ion exchange resin

Tae Young Kim; Sang Su An; Wang Geun Shim; Jea Wook Lee; Sung Young Cho; Jin Hwan Kim

Journal of Industrial and Engineering Chemistry, Vol.27, 260-267, July, 2015

DOI10.1016/j.jiec.2014.12.043 Export Citation

Adsorption and energetic heterogeneity properties of cesium ions on ion exchange resin

Tae Young Kim , Sang Su An¹, Wang Geun Shim², Jea Wook Lee³, Sung Young Cho, and Jin Hwan Kim^{2, †}

Department of Environment and Energy Engineering, Chonnam National University, Gwangju 500-757, Republic of Korea
¹Health & Environment Research Institute of Gwangju, Gwangju 502-270, Republic of Korea
²School of Applied Chemical Engineering, Chonnam National University, Gwangju 500-757, Republic of Korea
³Department of Chemical and Biochemical Engineering, Chosun University, Gwangju 590-170, Republic of Korea

E-mail:

The adsorption and energetic heterogeneity properties of cesium ion on ion exchange resin were investigated. The adsorption equilibrium isotherm of cesium ion on ion exchange resin could be represented by the Lamgmuir equation. Thermodynamic parameters indicated that adsorption of cesium ion on ion exchange resin was spontaneous and endothermic. Adsorption heterogeneity for the adsorption system of cesium ions on Amberlite IR 120 increased with increasing temperature and decreasing pH. A model based on linear driving force approximation was used for simulating the adsorption behavior of cesium ions in a fixed bed adsorber.

Keywords:Adsorption;Cesium;Equilibrium;Heterogeneity;Ion exchange resin

[References]

Dumat C, Quiquampoix H, Stuaunton S, Environ. Sci. Technol., 34, 2985 (2000)
Philip CV, Kim SH, Philip M, Anthony RG, Sep. Sci. Technol., 38(12-13), 3009 (2003)
Chakraborty D, Maji S, Bandyopadhyay A, Basu S, Bioresour. Technol., 98(15), 2949 (2007)
Stephen A, Stout A, Yunchul CB, Appl. Clay Sci., 31, 306 (2006)
Grossmann R, Maier HJ, Friebel HU, Frischke D, Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip., 480, 209 (2002)
Kim K, Kim K, Choi M, Son SH, Han JH, Chem. Eng. J., 189, 213 (2012)
Raut DR, Mohapatra PK, Choudhary MK, Nayak SK, J. Membr. Sci., 429, 197 (2013)
Nilchi A, Saberi R, Moradi M, Azizpour H, Zarghami R, Chem. Eng. J., 172(1), 572 (2011)
Lee CP, Kuo YM, Tsai SC, Wei YY, Teng SP, Hsu CN, J. Radioanal. Nucl. Chem., 275, 343 (2008)
Nilchia A, Atashib H, Javidc AH, Appl. Radiat. Isot., 65, 482 (2007)
Abd El-Latif MM, Elkady MF, Desalination, 255(1-3), 21 (2010)
Huang LD, Fu LL, Jin CW, Gielen G, Lin XTC, Wang HL, Zhang YS, Ecol. Eng., 37, 1515 (2011)
Jain AK, Gupta VK, Suhas SJ, Environ. Sci. Technol., 38, 1195 (2004)
Barkat M, Nibou D, Chearouche S, Mellah A, Chem. Eng. Process., 48(1), 38 (2009)
Podkoscielny P, Dabrowski A, Marijuk O, Appl. Surf. Sci., 205(1-4), 297 (2003)
Podkoscielny R, Laszlo K, Appl. Surf. Sci., 253(21), 8762 (2007)
Misic DM, Sudo Y, Suzuki M, Kawazeo K, J. Chem. Eng. Jpn., 15, 490 (1982)
Ma YH, Lee TY, AIChE J., 22, 147 (1976)
Traegner UK, Suidan MT, Water Res., 23, 267 (1989)
Wakao N, Funazkri, Chem. Eng. Sci., 33, 1375 (1978)
Reid RC, Prausnitz JM, Pokung BE, The Properties of Gases and Liquids, McGraw-Hill Co., New York, NY, 1994.
Kumar U, Bandyopadhyay M, J. Hazard. Mater., 129(1-3), 253 (2006)

[Referenced By]

[Related Articles]

[1] Dumat C, Quiquampoix H, Stuaunton S, Environ. Sci. Technol., 34, 2985 (2000)

[2] Philip CV, Kim SH, Philip M, Anthony RG, Sep. Sci. Technol., 38(12-13), 3009 (2003)

[3] Chakraborty D, Maji S, Bandyopadhyay A, Basu S, Bioresour. Technol., 98(15), 2949 (2007)

[4] Stephen A, Stout A, Yunchul CB, Appl. Clay Sci., 31, 306 (2006)

[5] Grossmann R, Maier HJ, Friebel HU, Frischke D, Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip., 480, 209 (2002)

[6] Kim K, Kim K, Choi M, Son SH, Han JH, Chem. Eng. J., 189, 213 (2012)

[7] Raut DR, Mohapatra PK, Choudhary MK, Nayak SK, J. Membr. Sci., 429, 197 (2013)

[8] Nilchi A, Saberi R, Moradi M, Azizpour H, Zarghami R, Chem. Eng. J., 172(1), 572 (2011)

[9] Lee CP, Kuo YM, Tsai SC, Wei YY, Teng SP, Hsu CN, J. Radioanal. Nucl. Chem., 275, 343 (2008)

[10] Nilchia A, Atashib H, Javidc AH, Appl. Radiat. Isot., 65, 482 (2007)

[11] Abd El-Latif MM, Elkady MF, Desalination, 255(1-3), 21 (2010)

[12] Huang LD, Fu LL, Jin CW, Gielen G, Lin XTC, Wang HL, Zhang YS, Ecol. Eng., 37, 1515 (2011)

[13] Jain AK, Gupta VK, Suhas SJ, Environ. Sci. Technol., 38, 1195 (2004)

[14] Barkat M, Nibou D, Chearouche S, Mellah A, Chem. Eng. Process., 48(1), 38 (2009)

[15] Podkoscielny P, Dabrowski A, Marijuk O, Appl. Surf. Sci., 205(1-4), 297 (2003)

[16] Podkoscielny R, Laszlo K, Appl. Surf. Sci., 253(21), 8762 (2007)

[17] Misic DM, Sudo Y, Suzuki M, Kawazeo K, J. Chem. Eng. Jpn., 15, 490 (1982)

[18] Ma YH, Lee TY, AIChE J., 22, 147 (1976)

[19] Traegner UK, Suidan MT, Water Res., 23, 267 (1989)

[20] Wakao N, Funazkri, Chem. Eng. Sci., 33, 1375 (1978)

[21] Reid RC, Prausnitz JM, Pokung BE, The Properties of Gases and Liquids, McGraw-Hill Co., New York, NY, 1994.

[22] Kumar U, Bandyopadhyay M, J. Hazard. Mater., 129(1-3), 253 (2006)