미세유체시스템을 이용한 셀룰로오스 마이크로 파이버의 제조

김성태; 조성립; 송민영; 장석태; Sung Tae Kim; Sung-rheb Cho; Minyung Song; Suk Tai Chang

Polymer(Korea), Vol.39, No.4, 588-592, July, 2015

DOI10.7317/pk.2015.39.4.588 Export Citation

미세유체시스템을 이용한 셀룰로오스 마이크로 파이버의 제조

Microfluidic Synthesis of Microfibers Based on Regeneration of Cellulose from Ionic Liquids

김성태, 조성립, 송민영, 장석태^†

중앙대학교 공과대학 화학신소재공학부

Sung Tae Kim, Sung-rheb Cho, Minyung Song, and Suk Tai Chang^†

School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul 156-756, Korea

E-mail:

초록

마이크로플루이딕 디바이스 내에서 셀룰로오스가 녹아있는 이온성 액체(1-에틸-3-메틸-이미다졸리움 아세테이트)로부터 셀룰로오스의 추출을 통한 직사각형의 단면적을 가지는 셀룰로오스 마이크로 파이버를 제조하였다. 본 연구에서 제안하는 방법은 빠른 시간 내에 간단하게 천연고분자 마이크로 파이버를 제작하기에 적합한 제조방법으로 적용가능하며, 이온성 액체와 주변 글리세린 용액의 유속비와 용액의 점도에 따라 다양한 크기의 셀룰로오스 마이크로 파이버를 제조하였다.

Rectangular cellulose microfibers were synthesized by regenerating cellulose from an ionic liquid, 1-ethyl-3-methylimidazolium acetate, in a hydrodynamic flow-focusing microfluidic device. This technique is a fast and single-step approach for producing natural polymer microfibers. The dimensions of the cellulose microfibers were readily controlled by a simple variation of the core-sheath flow rate and the viscosity of fluids.

Keywords:cellulose;microfibers;microfluidic system;ionic liquids

[References]

Rose M, Palkovits R, Macromol. Rapid Commun., 32(17), 1299 (2011)
Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)
Zhang H, Wang ZG, Zhang ZN, Wu J, Zhang J, He HS, Adv. Mater., 19(5), 698 (2007)
Kim J, Yun S, Ounaies Z, Macromolecules, 39(12), 4202 (2006)
O’sullivan AC, Cellulose, 4, 173 (1997)
Fink HP, Weigel P, Purz HJ, Ganster J, Prog. Polym. Sci, 26, 1473 (2001)
Jie XM, Cao YM, Lin B, Yuan Q, J. Appl. Polym. Sci., 91(3), 1873 (2004)
Swatloski RP, Spear SK, Holbrey JD, Rogers RD, J. Am. Chem. Soc., 124(18), 4974 (2002)
Zhu S, Wu Y, Chen Q, Yu Z, Wang C, Jin S, Ding Y, Wu G, Green Chem., 8, 325 (2006)
Sun N, Rahman M, Qin Y, Maxim ML, Rodriguez H, Rogers RD, Green Chem., 11, 646 (2009)
Kosan B, Michels C, Meister F, Cellulose, 15, 59 (2008)
Shin B, Cho MS, Kim D, Sim SJ, Kim JH, Lee DH, Nam JD, Lee Y, Polym.(Korea), 29(2), 216 (2005)
Xu SS, Zhang J, He AH, Li JX, Zhang H, Han CC, Polymer, 49(12), 2911 (2008)
Jung JH, Choi CH, Chung S, Chung YM, Lee CS, Lab Chip, 9, 2596 (2009)
Song M, Cho SR, Chang ST, Chem. Lett., 42(6), 577 (2013)
Marimuthu M, Kim S, An J, Soft Matter, 6, 2200 (2010)
Nunes JK, Wu CY, Amini H, Owsley K, Di Carlo D, Stone HA, Adv. Mater., 26(22), 3712 (2014)
Hwang S, Choi CH, Kim HC, Kim IH, Lee CS, Polym.(Korea), 36(2), 177 (2012)
Hwang CM, Khademhosseini A, Park Y, Sun K, Lee SH, Langmuir, 24(13), 6845 (2008)
Kim L, Vahey MD, Lee HY, Voldman J, Lab Chip, 6, 394 (2006)
Shah R, London AL, Laminar flow forced convection in ducts: a source book for compact heat exchanger analytical data, Academic Press, New York, 1978.
Zhang H, Wu J, Zhang J, He JS, Macromolecules, 38(20), 8272 (2005)
Cai T, Zhang HH, Guo QH, Shao HL, Hu XC, J. Appl. Polym. Sci., 115(2), 1047 (2010)

[Referenced By]

[1] Rose M, Palkovits R, Macromol. Rapid Commun., 32(17), 1299 (2011)

[2] Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)

[3] Zhang H, Wang ZG, Zhang ZN, Wu J, Zhang J, He HS, Adv. Mater., 19(5), 698 (2007)

[4] Kim J, Yun S, Ounaies Z, Macromolecules, 39(12), 4202 (2006)

[5] O’sullivan AC, Cellulose, 4, 173 (1997)

[6] Fink HP, Weigel P, Purz HJ, Ganster J, Prog. Polym. Sci, 26, 1473 (2001)

[7] Jie XM, Cao YM, Lin B, Yuan Q, J. Appl. Polym. Sci., 91(3), 1873 (2004)

[8] Swatloski RP, Spear SK, Holbrey JD, Rogers RD, J. Am. Chem. Soc., 124(18), 4974 (2002)

[9] Zhu S, Wu Y, Chen Q, Yu Z, Wang C, Jin S, Ding Y, Wu G, Green Chem., 8, 325 (2006)

[10] Sun N, Rahman M, Qin Y, Maxim ML, Rodriguez H, Rogers RD, Green Chem., 11, 646 (2009)

[11] Kosan B, Michels C, Meister F, Cellulose, 15, 59 (2008)

[12] Shin B, Cho MS, Kim D, Sim SJ, Kim JH, Lee DH, Nam JD, Lee Y, Polym.(Korea), 29(2), 216 (2005)

[13] Xu SS, Zhang J, He AH, Li JX, Zhang H, Han CC, Polymer, 49(12), 2911 (2008)

[14] Jung JH, Choi CH, Chung S, Chung YM, Lee CS, Lab Chip, 9, 2596 (2009)

[15] Song M, Cho SR, Chang ST, Chem. Lett., 42(6), 577 (2013)

[16] Marimuthu M, Kim S, An J, Soft Matter, 6, 2200 (2010)

[17] Nunes JK, Wu CY, Amini H, Owsley K, Di Carlo D, Stone HA, Adv. Mater., 26(22), 3712 (2014)

[18] Hwang S, Choi CH, Kim HC, Kim IH, Lee CS, Polym.(Korea), 36(2), 177 (2012)

[19] Hwang CM, Khademhosseini A, Park Y, Sun K, Lee SH, Langmuir, 24(13), 6845 (2008)

[20] Kim L, Vahey MD, Lee HY, Voldman J, Lab Chip, 6, 394 (2006)

[21] Shah R, London AL, Laminar flow forced convection in ducts: a source book for compact heat exchanger analytical data, Academic Press, New York, 1978.

[22] Zhang H, Wu J, Zhang J, He JS, Macromolecules, 38(20), 8272 (2005)

[23] Cai T, Zhang HH, Guo QH, Shao HL, Hu XC, J. Appl. Polym. Sci., 115(2), 1047 (2010)