Effect of alkyl side chain substitution on molecular structure of comb-like poly(2-hydroxyethyl methacrylate) derivatives

Eun-Ho Sohn; Dong-Jun Cho; Jin Woo Bae; Kigook Song

Macromolecular Research, Vol.23, No.8, 709-712, August, 2015

DOI10.1007/s13233-015-3107-0 Export Citation

Effect of alkyl side chain substitution on molecular structure of comb-like poly(2-hydroxyethyl methacrylate) derivatives

Eun-Ho Sohn, Dong-Jun Cho, Jin Woo Bae, and Kigook Song^†

Department of Advanced Materials Engineering for Information and Electronics, Kyung Hee University, Yongin, Gyeonggi, 446-701, Korea

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Long alkyl side chanis of comb-like poly(2-gydroxyethyl methacrylate) copolymers adopt differnet crystal structures simply because the copolymer has differnet degree of side chanin substiution. Differential scanning calorimetry (DSC), Fourier transform infrared (FTIR), and grazing incidence wide angle X-ray diffraction (GIWADXD) studies were employed to show various molecular structures, such as orthorhombic, hexagonal, and random phases, formed in side chain of the comb-like copolymer.

[References]

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Kim BG, Chung JS, Sohn EH, Kwak SY, Lee JC, Macromolecules, 42(9), 3333 (2009)
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[1] Wang JG, Mao GP, Ober CK, Krammer EJ, Macromolecules, 30(7), 1906 (1997)

[2] Kim BG, Chung JS, Sohn EH, Kwak SY, Lee JC, Macromolecules, 42(9), 3333 (2009)

[3] Sohn EH, Kim BG, Chung JS, Lee JC, J. Colloid Interface Sci., 343(1), 115 (2010)

[4] Sohn EH, Ahn J, Kim BG, Lee JC, Langmuir, 27(5), 1811 (2011)

[5] Sohn EH, Kim SH, Lee M, Lee JC, Song K, J. Colloid Interface Sci., 360(2), 623 (2011)

[6] Honda K, Morita M, Otsuka H, Takahara A, Macromolecules, 38(13), 5699 (2005)

[7] Shalaby WS, in Thermal Characterization of Polymeric Materials, Turi A, Ed., Academic, New York, 1981, p 334.

[8] Park SY, Farmer BL, Lee IC, J. Polym. Sci. B: Polym. Phys., 42(10), 1868 (2004)

[9] Corpart JM, Girault S, Juhue D, Langmuir, 17(23), 7237 (2001)

[10] Kasemura T, Takahashi S, Nakane N, Maegawa T, Polymer, 37(16), 3659 (1996)

[11] Grundke K, Zschoche S, Poschel K, Gietzelt T, Michel S, Friedel P, Jehnichen D, Neumann AW, Macromolecules, 34(19), 6768 (2001)

[12] Okouchi M, Yamaji Y, Yamauchi K, Macromolecules, 39(3), 1156 (2006)

[13] Macphail RA, Strauss HL, Snyder RG, Elliger CA, J. Phys. Chem., 88, 334 (1984)

[14] Kim DG, Lim H, Choi SN, Kim SS, Song K, Polym.(Korea), 26(6), 752 (2002)

[15] Zhon Y, Shi H, Zhao Y, Men Y, Jiang S, Rottstegge J, Wang D, CrystEngComm, 13, 501 (2011)

[16] Sohn EH, Kang H, Kim DG, Song K, Lee JC, Chem. Phys. Chem., 13, 2061 (2012)

[17] Hsieh HW, Post B, Morawetz H, Polym. Sci. Polym. Phys., 14, 1241 (1976)

[18] Lee JC, Han SH, Cha SH, Park SY, Farmer BL, Polymer, 44(24), 7413 (2003)

[19] Kaufman HS, Sacher A, Alfrey T, Fankuchen I, J. Am. Chem. Soc., 70, 3147 (1948)

[20] Lopez-Carrasquero F, de Ilarduya AM, Cardenas M, Carrillo M, Arnal ML, Laredo E, Torres C, Mendez B, Muller AJ, Polymer, 44(17), 4969 (2003)

[21] Carrillo M, de Ilarduya AM, Arnal ML, Torres C, Lopez-Carrasquero F, Polym. Bull., 48(1), 59 (2002)