화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.39, No.5, 809-813, September, 2015
DOI10.7317/pk.2015.39.5.809  Export Citation
폴리염화비닐/PB-g-PMMA 복합재의 특징
Properties of Poly(vinyl chloride)/PB-g-PMMA Composites
Guangfeng Wu†, Hailong Zhang, and Huixuan Zhang
  • Engineering Research Center of Synthetic Resin and Special Fiber, Ministry of Education, Changchun University of Technology, Changchun 130012, P.R. China
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To improve the mechanical properties of poly(vinyl chloride) (PVC), the characters of combining PVC with elastomers were considered. Polybutadiene grafted poly(methyl methacrylate) (PB-g-PMMA, MB) core-shell particles were prepared by emulsion polymerization, and were used as an impact modifier for PVC. The impact resistance, fracture, brittle-ductile transition and the morphology of PVC/MB blends were investigated. It was found that MB particles had a high toughening efficiency for PVC resin, the impact strength was more than 1100 J·m-1 when MB was 8 phr. Two factors influence the impact strength and brittle-ductile transition, one is the modifier content, and the other is core-shell weight ratio. The impact curves are Ω-like shape, the impact strength value is the highest at the middle part and the PVC/MB blends show ductile break behaviors. The core shell ratio of ductile areas are limited from 80/20 to 90/10 for PVC/MB=100/8, and 70/30 to 93/7 for PVC/MB=100/10.
Keywords:polymer composite;toughened;brittle-ductile transition;core-shell particles
  1. Norbert P, J. Polym. Sci.: Polym. Lett. Ed., 18, 643 (1980)
  2. Wu SH, Polymer, 26, 1855 (1985)
  3. Wu SH, Polym. Eng. Sci., 30, 753 (1990)
  4. Liu ZH, Zhu XG, Wu LX, Li Y, Qi ZN, Choy C, Wang FS, Polymer, 42(2), 737 (2001)
  5. Liu ZH, Zhang XD, Zhu XG, Li RKY, Qi ZN, Wang FS, Choy CL, Polymer, 39(21), 5019 (1998)
  6. Liu ZH, Zhang XD, Zhu XG, Qi ZN, Wang FS, Li RKY, Choy CL, Polymer, 39(21), 5027 (1998)
  7. Liu ZH, Zhu XG, Li Q, Qi ZN, Wang FS, Polymer, 39(10), 1863 (1998)
  8. Michael MC, Paul CP, John FG, Specific Interactions and the Miscibility of Polymer Blends, Technomic Publishing Co., Pennsylvania, 1995.
  9. Kolarik J, Landro LD, Pegoraro M, J. Mater. Sci. Lett., 9, 876 (1990)
  10. Wu GF, Zhao JF, Shi HT, Zhang HX, Eur. Polym. J., 40, 2451 (2004)
  11. Perkins WG, Polym. Eng. Sci., 39(12), 2445 (1999)
  12. Parker DS, Sue HJ, Huang J, Yee AF, Polymer, 31, 2267 (1990)
  13. Yanagase A, Ito M, Yamamoto N, Ishikawa M, J. Appl. Polym. Sci., 60(1), 87 (1996)
  14. Lim JC, Min KE, Polym.(Korea), 20(4), 558 (1996)
  15. Liu ZH, Zhang XD, Zhu XG, Li RKY, Qi ZN, Wang FS, Choy CL, Polymer, 39(21), 5035 (1998)