화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.32, No.9, 1864-1878, September, 2015
Two-stage batch sorber design and optimization of biosorption conditions by Taguchi methodology for the removal of acid red 25 onto magnetic biomass
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Biomagnetic material (MFC) was synthesized via simple co-precipitation and used as biosorbent for the removal of acid red 25 (AR25) under optimized conditions. The characteristics of MFC were studied using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM), Boehm titration and scanning electron microscopy (SEM). Optimum removal of AR25 was achieved at pH=5.0. The equilibrium data were well described by the Sips and Freundlich models. Taguchi methodology was employed to optimize the biosorption experiments. 411.56mg/g and 96.8% were obtained as the biosorption capacity and removal efficiency, respectively, at the optimum conditions of ionic strength (0.5M), influent volume (300 L) and MFC dosage (4 g). The contact time for removal of 96% AR25 in two-stage batch system is 400.8min which is lower than the single-stage treatment process (895 min).
  1. Ahmad AA, Hameed BH, Aziz N, J. Hazard. Mater., 141(1), 70 (2007)
  2. Hameed BH, El-Khaiary MI, J. Hazard. Mater., 159(2-3), 574 (2008)
  3. Ho YS, McKay G, Can. J. Chem. Eng., 76(4), 822 (1998)
  4. Oladipo AA, Gazi M, Sabar-Samandari S, J. Taiwan Inst. Chem. Eng., 45, 653 (2014)
  5. Rashid K, Reddy SK, Shoaibi AA, Srinivasakannan C, Can. J. Chem. Eng., 9999, 1 (2013)
  6. Zhu HY, Fu YQ, Jiang R, Jiang JH, Xiao L, Zeng GM, Zhao SL, Wang Y, Chem. Eng. J., 173(2), 494 (2011)
  7. Ayad MM, El-Nasr AA, J. Nanostruct. Chem., 3, 3 (2012)
  8. Jain S, Jayaram RV, Desalination, 250(3), 921 (2010)
  9. Nethaji S, Sivasamy A, Thennarasu G, Saravanan S, J. Hazard. Mater., 181(1-3), 271 (2010)
  10. Thamilarasu P, Karunakaran K, Can. J. Chem. Eng., 91(1), 9 (2013)
  11. Thevannan A, Hill G, Niu CH, Can. J. Chem. Eng., 89(1), 176 (2011)
  12. Zhang WX, Li HJ, Kan XW, Dong L, Yan H, Jiang ZW, Yang H, Li AM, Cheng RS, Bioresour. Technol., 117, 40 (2012)
  13. Chowdhury S, Chakraborty S, Saha PD, Environ. Sci. Pollut. Res., 20, 1698 (2013)
  14. Kadirvelu K, Thamaraiselvi K, Namasivayam C, Sep. Purif. Technol., 24(3), 497 (2001)
  15. Ofomaja AE, Unuabonah EI, J. Taiwan Inst. Chem. Eng., 44, 566 (2013)
  16. Ozdes D, Gundogdu A, Kemer B, Duran C, Kucuk M, Soylak M, Can. J. Chem. Eng., 92(1), 139 (2014)
  17. Sarin V, Pant KK, Bioresour. Technol., 97(1), 15 (2006)
  18. Vijayaraghavan K, Jegan J, Palanivelu K, Velan M, Sep. Purif. Technol., 44(1), 53 (2005)
  19. Yu JX, Wang LY, Chi RA, Zhang YF, Xu XG, Guo J, Environ. Sci. Pollut. Res., 20, 543 (2013)
  20. Maggi F, Cecchini C, Cresci A, Coman MM, Tirillini B, Sagratini G, Fabrizio P, Fitoterapia, 80, 68 (2009)
  21. Marchi A, Appendino G, Pirisi I, Ballero M, Loi MC, Biochem. System. Ecolog., 31, 1397 (2003)
  22. Seki Y, Sarikanat M, Sever K, Durmuskahya C, Composites: Part B, 44, 517 (2013)
  23. Deni F, Env. Prog. Sust. Energy, 32, 1129 (2013)
  24. Liu J, Li Y, Li K, J. Env. Chem. Eng., 1, 389 (2013)
  25. Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A, J. Hazard. Mater., 186(1), 891 (2011)
  26. Oladipo AA, Gazi M, J. Water Process Eng., 2, 43 (2014)
  27. Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean J. Chem. Eng., 31(6), 1021 (2014)
  28. Tang H, Zhou W, Zhang L, J. Hazard. Mater., 209-210, 218 (2012)
  29. Mahmoodi NM, Hayati B, Arami M, Lan C, Desalination, 268(1-3), 117 (2011)
  30. Zhang WX, Yan H, Li HJ, Jiang ZW, Dong L, Kan XW, Yang H, Li AM, Cheng RS, Chem. Eng. J., 168(3), 1120 (2011)
  31. Basha S, Murthy ZVP, Jha B, Chem. Eng. J., 147(2-3), 226 (2009)
  32. Ho YS, Wang CC, J. Hazard. Mater., 156(1-3), 398 (2008)
  33. Ozacar M, Sengyl IA, Biochem. Eng. J., 21, 39 (2004)
  34. Akar ST, Balk YY, Tuna O, Akar T, Carbohydr. Polym., 94, 400 (2013)
  35. Liu Y, Chen M, Hao YM, Chem. Eng. J., 218, 46 (2013)
  36. Shao LN, Ren ZM, Zhang GS, Chen LL, Mater. Chem. Phys., 135(1), 16 (2012)
  37. Zhang G, Qu J, Liu H, Cooper AT, Wu R, Chemosphere, 68, 1058 (2007)
  38. Tu YJ, You CF, Chang CK, Chan TS, Li SH, Chem. Eng. J., 244, 343 (2014)
  39. Oladipo AA, Gazi M, J. Taiwan Inst. Chem. Eng., DOI:10.1016/j.jtice.2014.09.027. (2014)
  40. Akar T, Balk YY, Tuna O, Akar ST, Ecolog. Eng., 61, 251 (2013)
  41. Elkady MF, Ibrahim AM, Abd El-Latif MM, Desalination, 278(1-3), 412 (2011)
  42. Chiou MS, Li HY, Chemosphere, 50, 1095 (2003)
  43. Crini G, Badot PM, Prog. Polym. Sci, 33, 399 (2008)
  44. Makeswari M, Santhi T, J. Chem., 2013, 12 (2012)
  45. Ofomaja AE, Biochem. Eng., 40, 8 (2008)
  46. Alberghina G, Bianchini R, Fichera M, Fisichella S, Dyes Pigment., 46, 129 (2000)
  47. Al-Degs YS, El-Barghouthi MI, El-Sheikh AH, Walker GM, Dyes Pigment., 77, 16 (2008)
  48. Li Q, Yue QY, Su Y, Gao BY, Sun HJ, Chem. Eng. J., 158(3), 489 (2010)
  49. Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
  50. Shirmardi M, Mesdaghinia A, Mahvi AH, Nasseri S, Nabizadeh R, J. Chem., 9, 2371 (2012)
  51. Gomez V, Larrechi MS, Callao MP, Chemosphere, 69, 1151 (2007)
  52. Shokoohi R, Vatanpoor V, Zarrabi M, Vatani A, J. Chem., 7, 65 (2010)
  53. Shirzad-Siboni M, Khataee A, Vafaei F, Joo SW, Korean J. Chem. Eng., 31(8), 1451 (2014)
  54. Oladipo AA, Gazi M, Toxicol. Env. Chem., DOI:10.1080/02772248.2014.989854. (2014)
  55. Oladipo AA, Gazi M, J. Water Process Eng., 10.1016/j.jwpe.2014.12.002. (2014)
  56. Sips R, J. Chem. Phys., 16, 490 (1948)
  57. Mittal A, J. Hazard. Mater., 133(1-3), 196 (2006)
  58. Tan IAW, Ahmad AL, Hameed BH, Chem. Eng. J., 137(3), 462 (2008)
  59. Farah JY, El-Gendy NS, Turkish J. Eng. Env. Sci., 37, 146 (2013)
  60. Ofomaja AE, Unuabonah EI, Carbohydr. Polym., 83, 1192 (2011)
  61. Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90 (2005)
  62. Zhang WX, Yan H, Li HJ, Jiang ZW, Dong L, Kan XW, Yang H, Li AM, Cheng RS, Chem. Eng. J., 168(3), 1120 (2011)
  63. Zhang WX, Dong L, Yan H, Li HJ, Jiang ZW, Kan XW, Yang H, Li AM, Cheng RS, Chem. Eng. J., 173(2), 429 (2011)