Enhanced copper(II) biosorption on SiO2-alginate gel composite: A mechanistic study with surface characterization

Sibel Yalcın; Reşat Apak; Ismail Boz

Korean Journal of Chemical Engineering, Vol.32, No.10, 2116-2123, October, 2015

DOI10.1007/s11814-015-0051-9 Export Citation

Enhanced copper(II) biosorption on SiO2-alginate gel composite: A mechanistic study with surface characterization

Sibel Yalcın^†, Reşat Apak, and Ismail Boz

Chemistry Department, Faculty of Engineering, Istanbul University, Avcilar 34320, Istanbul, Turkey

E-mail:

A new SiO2-alginate biocomposite was synthesized with improved mechanical properties, showing chelation capability of divalent metal ions, especially Cu(II), through its carboxylic acid ends. The biocomposite was characterized using scanning electron microscopy (SEM), Fourier-transform infrared (FTIR), and X-ray photoelectron spectroscopy (XPS) techniques. The adsorption of copper(II) onto both H- and Ca-forms of sorbent was investigated as a function of pH and contact time, and adsorption data were modeled with the aid of Langmuir and Freundlich isotherms. The release of Ca(II) ions accompanying copper(II) binding was evaluated by selective surface complexation concept involving ion-exchange. The IR spectra gave detailed information on complexation of carbonyl group with copper ions and on the relative contribution of SiO2 involved in copper uptake. The adsorption edge of copper was within the pH range 4.0-5.5, and the sorbent capacity was determined as 1.85 and 1.10mmolg.1 for H- and Ca-forms, respectively.

Keywords:Alginate-SiO2 Biocomposite;Cu(II) Adsorption;FTIR-XPS Analyses;Surface Characterization

[References]

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[2] Davis TA, Volesky B, Mucci A, Water Res., 37(18), 4311 (2003)

[3] Yalcin S, Sezer S, Apak R, Environ. Sci. Pollut. Res., 19(8), 3118 (2012)

[4] Chmielewska E, Sabova L, Peterlik L, Wu A, Braz. J. Chem. Eng., 28(1), 63 (2011)

[5] Li Y, Xia B, Zhao Q, Liu F, Zhang P, Du Q, Wang D, Li D, Wang Z, Xia Y, J. Environ. Sci., 23(3), 404 (2011)

[6] Murphy V, Hughes H, McLoughlin P, Water Res., 41(4), 731 (2007)

[7] Lima IS, Airoldi C, Colloids Surf. A: Physicochem. Eng. Asp., 229(1-3), 129 (2003)

[8] Davila-Guzman NE, de J. Cerino-Cordova F, Soto-Regalado E, Soto-Regalado E, Soto-Regalado JR, Diaz-Flores PE, Garza-Gonzalez MT, Loredo-Medrano JA, Clean., 41(6), 557 (2013)

[9] Tam SK, Dusseault J, Polizu S, Menard M, Halle JP, Yahia LH, Biomaterials, 26(34), 6950 (2005)

[10] Serra J, Gonzalez P, Liste S, Serra C, Chiussi S, Leon B, Perez-Amor M, Ylanen HO, Hupa M, J. Non-Cryst. Solids, 332(1-3), 20 (2003)

[11] Figueira MM, Volesky B, Mathieu HJ, Environ. Sci. Technol., 33(11), 1840 (1999)

[12] Chen J, Tendeyong F, Yiacoumi S, Environ. Sci. Technol., 31(5), 1433 (1997)

[13] Wang FC, Zhao JM, Pan F, Zhou HC, Yang XF, Li WS, Liu HZ, Ind. Eng. Chem. Res., 52(9), 3453 (2013)

[14] Choi JW, Yang KS, Kim DJ, Lee CE, Curr. Appl. Phys., 9(3), 694 (2009)

[15] Park HG, Kim TW, Chae MY, Yoo IK, Process Biochem., 42(10), 1371 (2007)

[16] Luna-Lopez JA, Carrillo-Lopez J, Aceves-Mijares M, Morales-Sanchez A, Falcony C, Superficies y Vacio, 22(1), 11 (2009)

[17] Al-Oweini R, El-Rassy H, J. Mol. Struct., 919(1-3), 140 (2009)

[18] Torres E, Mata YN, Blazquez AL, Munoz JA, Gonzalez F, Ballester A, Langmuir, 21(17), 7951 (2005)

[19] Lim SF, Zheng YM, Zou SW, Chen JP, Environ. Sci. Technol., 42(7), 2551 (2008)

[20] Fourest E, Volesky B, Environ. Sci. Technol., 30(1), 277 (1996)

[21] Yalcin S, Clean., 42(3), 251 (2014)

[22] Kleinubing SJ, Vieira RS, Beppu MM, Guibal E, da Silva MGC, Mat. Res, 13(4), 541 (2010)

[23] Broderick E, Lyons H, Pembroke T, Byrne H, Murray B, Hall M, J. Colloid Interface Sci., 298(1), 154 (2006)

[24] Czanderna AW, King DE, Spaulding D, J. Vac. Sci. Technol. A, 9(5), 2607 (1991)

[25] Papageorgiou SK, Katsaros FK, Kouvelos EP, Nolan JW, Le Deit H, Kanellopoulos NK, J. Hazard. Mater., 137(3), 1765 (2006)

[26] Chen JP, Hong LA, Wu SN, Wang L, Langmuir, 18(24), 9413 (2002)

[27] Sheng PX, Ting YP, Chen JP, Hong L, J. Colloid Interface Sci., 275(1), 131 (2004)

[28] Cheng X, Guan H, Su Y, J. Inorg. Organomet. Polym., 10(3), 115 (2000)

[29] Figueira MM, Volesky B, Ciminelli VST, Roddick FA, Water Res., 34(1), 196 (2000)

[30] Haug A, Acta. Chem. Scand., 15(8), 1794 (1961)

[31] Jeon C, Park JY, Yoo YJ, Water Res., 36(7), 1814 (2002)

[32] Rengaraj S, Yeon JW, Kim Y, Jung Y, Ha YK, Kim WH, J. Hazard. Mater., 143(1-2), 469 (2007)

[33] Masel RI, Principles of Adsorption and Reaction on Solid Surfaces, Wiley-Interscience, New York (1996).

[34] Sposito G, Soil Sci. Soc. Am. J., 46(6), 1147 (1982)

[35] Wase J, Foster CF, Biosorbents for Metal Ions, Taylor & Francis Ltd., London, United Kingdom (1997).