Fine control of particle size by seeding and ageing under agitation in the synthesis of analcime zeolite

Soon Hee Park; Jong-Ho Kim; Chang-Bock Chung; Gon Seo

Korean Journal of Chemical Engineering, Vol.32, No.12, 2512-2518, December, 2015

DOI10.1007/s11814-015-0090-2 Export Citation

Fine control of particle size by seeding and ageing under agitation in the synthesis of analcime zeolite

Soon Hee Park, Jong-Ho Kim , Chang-Bock Chung , and Gon Seo^†

Department of Chemical Engineering and the Research Institute for Catalysis, Chonnam National University, 77, Yongbong-ro, Buk-gu, Gwangju 500-757, Korea

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The size of analcime particles produced through hydrothermal reactions of alkaline synthesis mixtures was finely controlled by seeding and ageing under agitation. Adding acid-treated analcime seeds to the synthesis mixture followed by ageing in an agitated vessel facilitated further nucleation, which resulted in the formation of fine analcime particles with an extremely narrow size distribution. The size of analcime particles could be controlled in the range of 0.5-5.0 μm with a standard deviation of less than 0.1 μm by varying the amount and type of the acid-treated seeds, the ageing time, and the agitation speed.

Keywords:Analcime;Particle Size;Seeding;Ageing;Agitation

[References]

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Szostak R, Molecular sieves: Principles of synthesis and identification, Van Nostrand Reinhold, New York (1989).
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Park SE, Jiang N, in Zeolites and catalysis, Cejka J, Corma A, Zones S, Eds., WILEY-VCH, Weinheim (2010).
Tosheva L, Valtchev VP, Chem. Mater., 17, 2494 (2005)
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Wang C, Li J, Yan J, Sun J, Korean J. Chem. Eng., 31(9), 1547 (2014)
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Kaeding WW, J. Catal., 95, 512 (1985)
Lee KY, Chae HJ, Jeong SY, Seo G, Appl. Catal. A: Gen., 369(1-2), 60 (2009)
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Ren N, Yang ZJ, Lv XC, Shi J, Zhang YH, Tang Y, Microporous Mesoporous Mater., 131, 103 (2010)
Park SH, Chung CB, Seo G, Microporous Mesoporous Mater., 155, 201 (2012)
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Pan Y, Ju M, Yao J, Zhang L, Xu N, Chem. Commun., 46, 7233 (2009)

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[1] Barrer RM, Hydrothermal chemistry of zeolites, Academic Press, London (1982).

[2] Breck DW, Zeolite molecular sieves, John Wiley & Sons, New York (1974).

[3] Szostak R, Molecular sieves: Principles of synthesis and identification, Van Nostrand Reinhold, New York (1989).

[4] Robson H, Ed., Verified syntheses of zeolitic materials, Elsevier, Amsterdam (2001).

[5] Zhdanov SP, Khvoshchev SS, Feoktistova NN, Synthetic zeolites, Gordon and Breach Science Publishers, Amsterdam (1990).

[6] Jihong Y, in Introduction to zeolite science and practice, Cejka J, Bekkum H, Corma A, Schuth F, Eds., Elsevier, Amsterdam (2007).

[7] Park SE, Jiang N, in Zeolites and catalysis, Cejka J, Corma A, Zones S, Eds., WILEY-VCH, Weinheim (2010).

[8] Tosheva L, Valtchev VP, Chem. Mater., 17, 2494 (2005)

[9] Brar T, France P, Smirniotis PG, Ind. Eng. Chem. Res., 40(4), 1133 (2001)

[10] Wang C, Li J, Yan J, Sun J, Korean J. Chem. Eng., 31(9), 1547 (2014)

[11] Ko YS, Ahn WS, Korean J. Chem. Eng., 25(6), 1546 (2008)

[12] Sharma P, Rajaram P, Tomar R, J. Colloid Interface Sci., 325(2), 547 (2008)

[13] Di Renzo F, Catal. Today, 41(1-3), 37 (1998)

[14] Wiersema GS, Thompson RW, J. Mater. Chem., 6, 1693 (1996)

[15] Cundy CS, Cox PA, Microporous Mesoporous Mater., 82, 1 (2005)

[16] Subotic B, Bronic J, in Handbook of zeolite science and technology, Auerbach SM, Carrado KA, Dutta PK, Eds., Marcel Dekker, New York (2003).

[17] Lee CH, Park SW, Kim SS, Korean J. Chem. Eng., 31(2), 179 (2014)

[18] Kaeding WW, J. Catal., 95, 512 (1985)

[19] Lee KY, Chae HJ, Jeong SY, Seo G, Appl. Catal. A: Gen., 369(1-2), 60 (2009)

[20] Thompson RW, in Molecular sieves: Synthesis, Karge HG, Weitkamp J, Eds., Springer, New York (1998).

[21] Majano G, Darwiche A, Mintova S, Valtchev V, Ind. Eng. Chem. Res., 48(15), 7084 (2009)

[22] Ren N, Yang ZJ, Lv XC, Shi J, Zhang YH, Tang Y, Microporous Mesoporous Mater., 131, 103 (2010)

[23] Park SH, Chung CB, Seo G, Microporous Mesoporous Mater., 155, 201 (2012)

[24] Treacy MMJ, Higgins JB, Collection of simulated XRD powder patterns for zeolites, Elsevier, New York (2007).

[25] Pan Y, Ju M, Yao J, Zhang L, Xu N, Chem. Commun., 46, 7233 (2009)