화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.28, 60-66, August, 2015
DOI10.1016/j.jiec.2015.01.023  Export Citation
Magnetic chitosan composite for adsorption of cationic and anionic dyes in aqueous solution
Dong-Wan Cho, Byong-Hun Jeon1, †, Chul-Min Chon2, Franklin W. Schwartz3, Yoojin Jeong, and Hocheol Song†
  • Department of Environment and Energy, Sejong University, Seoul 143-747, South Korea
  • 1Department of Natural Resources and Environmental Engineering, Hanyang University, 2226 Wangsimni-ro, Seongdong-gu, Seoul 133-791, South Korea
  • 2Geologic Environment Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 305-350, South Korea
  • 3School of Earth Sciences, The Ohio State University, Columbia, OH 43210, USA
E-mail:,
A magnetic composite material composed of nano-magnetite (NMT), heulandite (HE), and cross-linked chitosan was prepared and used as an adsorbent for methylene blue (MB) and methyl orange (MO). The composite was characterized for the morphology, magnetic and surface properties. The optimal mass ratio of chitosan:HE:NMT for the best removal of both dyes was determined to be 1:1:0.33. The adsorption of MB and MO followed the pseudo-second order kinetics, and the maximum adsorption capacities were 45.1 and 149.2 mg g -1 1 at pH 5.5, respectively. The adsorption of MB increased with the pH increase, while MO adsorption showed an opposite trend.
Keywords:Methylene blue;Methyl orange;Chitosan;Clay;Magnetite
  1. Ali H, Water Air Soil Pollut., 213, 251 (2010)
  2. Kertesz S, Cakl J, Jirankova H, Desalination, 343, 106 (2014)
  3. Vimonses V, Lei S, Jin B, Chow CWK, Saint C, Appl. Clay Sci., 43, 465 (2009)
  4. Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
  5. Yang ST, Chen S, Chang YL, Cao AN, Liu YF, Wang HF, J. Colloid Interface Sci., 359(1), 24 (2011)
  6. Cao J, Luo B, Lin H, Chen S, J. Hazard. Mater., 218, 107 (2012)
  7. Li X, Ni C, Yao C, Chen Z, Appl. Catal. B: Environ., 117-118, 118 (2012)
  8. Majewska-Nowak K, Kowalska I, Kabsch-Korbutowicz M, Desalination, 198(1-3), 149 (2006)
  9. Ong SA, Toorisaka E, Hirata M, Hano T, J. Hazard. Mater., 124(1-3), 88 (2005)
  10. Golder AK, Hridaya N, Samanta AN, Ray S, J. Hazard. Mater., 127(1-3), 134 (2005)
  11. Divya N, Bansal A, Jana AK, Int. J. Biol. Chem. Sci., 54 (2009)
  12. Blackburn RS, Environ. Sci. Technol., 38, 4905 (2004)
  13. Jain AK, Gupta VK, Bhatnagar A, Suhas, J. Hazard. Mater., 101(1), 31 (2003)
  14. Fan LL, Luo CN, Sun M, Li XJ, Lu FG, Qiu HM, Bioresour. Technol., 114, 703 (2012)
  15. Kyzas GZ, Lazaridis NK, Mitropoulos AC, Chem. Eng. J., 189-190, 148 (2012)
  16. Ngah WSW, Ab Ghani S, Kamari A, Bioresour. Technol., 96(4), 443 (2005)
  17. Guibal E, Sep. Purif. Technol., 38(1), 43 (2004)
  18. Chen AH, Liu SC, Chen CY, Chen CY, J. Hazard. Mater., 154(1-3), 184 (2008)
  19. Sureshkumar MK, Das D, Mallia MB, Gupta PC, J. Hazard. Mater., 184(1-3), 65 (2010)
  20. Zhu HY, Jiang R, Xiao L, Zeng GM, Bioresour. Technol., 101(14), 5063 (2010)
  21. Fahim I, Kheireddine A, Belaaouad S, J. Optoelectron. Adv. Mater., 15, 451 (2013)
  22. Ngah WSW, Fatinathan S, J. Environ. Manage., 91, 958 (2010)
  23. Pan JM, Yao H, Li XX, Wang B, Huo PW, Xu WZ, Ou HX, Yan YS, J. Hazard. Mater., 190(1-3), 276 (2011)
  24. Cho DW, Chon CM, Kim Y, Jeon BH, Schwartz FW, Lee ES, Song H, Chem. Eng. J., 200-202, 654 (2012)
  25. Sikder MT, Mihara Y, Islam MS, Saito T, Tanaka S, Kurasaki M, Chem. Eng. J., 236, 378 (2014)
  26. Ozacar M, Sengil IA, J. Environ. Manage., 80, 372 (2006)
  27. Zhu HY, Jiang R, Xiao L, Appl. Clay Sci., 48, 522 (2010)
  28. Perraki T, Orfanoudaki A, Appl. Clay Sci., 25, 9 (2004)
  29. Zawadzki J, Kaczmarek H, Carbohydr. Polym., 80, 394 (2010)
  30. Riese HC, Am. Mineral., 52, 1198 (1967)
  31. Wang YF, Bryan C, Xu HF, Pohl P, Yang Y, Brinker CJ, J. Colloid Interface Sci., 254(1), 23 (2002)
  32. Vodyanitskii YN, Morgun EG, Obydenova LA, Rumyantseva KA, Chapygina NV, Geochem. Int., 47, 297 (2009)
  33. Chatterjee S, Chatterjee S, Chatterjee BP, Das AR, Guha AK, J. Colloid Interface Sci., 288(1), 30 (2005)
  34. Asuha S, Gao YW, Deligeer W, Yu M, Suyala B, Zhao S, J. Porous Mat., 18, 581 (2011)
  35. Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
  36. Oladoja NA, Aboluwoye CO, Oladimeji YB, Turk. J. Eng. Environ. Sci., 32, 303 (2008)
  37. Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)
  38. Huang XY, Bin JP, Bu HT, Jiang GB, Zeng MH, Carbohydr. Polym., 84, 1350 (2011)
  39. Das D, Sureshkumar MK, Radhakrishnan K, Nuwar J, Pillai CGS, J. Radioanal. Nucl. Chem., 289, 275 (2011)
  40. Ngah WSW, Fatinathan S, Chem. Eng. J., 143(1-3), 62 (2008)
  41. Chiou MS, Li HY, Chemosphere, 50, 1095 (2003)
  42. Debrassi A, Correa AF, Baccarin T, Nedelko N, Slawska-Waniewska A, Sobczak K, Dluzewski P, Greneche JM, Rodrigues CA, Chem. Eng. J., 183, 284 (2012)
  43. Liu Y, Zheng Y, Wang A, J. Environ. Sci, 22, 486 (2010)
  44. Xing Y, Sun XM, Li BH, Environ. Eng. Sci, 26, 551 (2009)
  45. Jiang R, Fu YQ, Zhu HY, Yao J, Xiao L, J. Appl. Polym. Sci., 125, E540 (2012)
  46. Zhang JX, Zhou QX, Ou LL, J. Chem. Eng. Data, 57(2), 412 (2012)