Novel biocidal N-halamine plastic based on poly(vinyl chloride): Preparation and characteristics

Marta Chylinska; Halina Kaczmarek; Aleksandra Burkowska-But; Maciej Walczak

Journal of Industrial and Engineering Chemistry, Vol.28, 124-130, August, 2015

DOI10.1016/j.jiec.2015.02.007 Export Citation

Novel biocidal N-halamine plastic based on poly(vinyl chloride): Preparation and characteristics

Marta Chylinska, Halina Kaczmarek^†, Aleksandra Burkowska-But¹, and Maciej Walczak¹

Faculty of Chemistry, Department of Chemistry and Photochemistry of Polymers, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, Poland
¹Faculty of Biology and Environmental Protection, Department of Environment Microbiology and Biotechnology, Nicolaus Copernicus University in Torun, Lwowska 1, 87-100 Torun, Poland

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Preparation method of new biocidal plastics based on plasticized PVC has been elaborated. The derivative of poly(4-vinylbenzyl chloride) containing N-halamine substituents has been mixed with PVC granules and processed by dry blend extrusion and injection moulding. The properties of obtained material have been tested using SEM/EDX and thermogravimetry. The biocidal efficacy of modified PVC resin has been tested against two strains of bacteria: Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive). It was found that even small amount of biocidal component yields to efficient biocidal activity of the whole plastic. Chemical composition and other properties of PVC remain almost unchanged.

Keywords:Poly(vinyl chloride);N-halamine;Hydantoin;Biocidal activity;Thermal properties

[References]

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Shin HK, Park M, Chung YS, Kim HY, Jin FL, Park SJ, J. Ind. Eng. Chem., 20(4), 1476 (2014)
Hui F, Debiemme-Chouvy C, Biomacromolecules, 14(3), 585 (2013)
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Moulay S, Prog. Polym. Sci, 35, 303 (2010)
Piszczek K, Sterzynski T, Lukaszewicz E, Polym. Test, 22, 115 (2003)
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Senna MMH, Hussein YA, Abdel-Moneam YK, Polym. Compos., 29, 1049 (2008)
Chylinska M, Ziegler-Borowska M, Kaczmarek H, Burkowska A, Walczak M, Kosobucki P, E-Polymers, 14, 15 (2014)
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Chylinska M, Kaczmarek H, Thermochim. Acta, 583, 32 (2014)
Gour N, Ngo KX, Vebert-Nardin C, Macromol. Mater. Eng., 299, 648 (2014)
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Starnes WH, Prog. Polym. Sci, 27, 2133 (2007)
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Saeki Y, Emura T, Prog. Polym. Sci, 27, 2055 (2002)

[Referenced By]

[1] Sun YY, Chen TY, Worley SD, Sun G, J. Polym. Sci. A: Polym. Chem., 39(18), 3073 (2001)

[2] Luo J, Sun Y, J. Polym. Sci. A: Polym. Chem., 44, 3588 (2004)

[3] Kocer HB, Akdag A, Worley SD, Acevedo O, Broughton RM, Wu Y, ACS Appl. Mater. Interfaces, 2, 2456 (2010)

[4] Shin HK, Park M, Chung YS, Kim HY, Jin FL, Park SJ, J. Ind. Eng. Chem., 20(4), 1476 (2014)

[5] Hui F, Debiemme-Chouvy C, Biomacromolecules, 14(3), 585 (2013)

[6] Dhar TGM, Potin D, Maillet MJB, Launay M, Nicolai EA, Iwanowicz EJ, U.S. Patent 7078420 B2, 2006.

[7] Badrossamay MR, Sun G, J. Biomed. Mater. Res. Part B: Appl. Biomater., 89B, 93 (2009)

[8] Badrossamay MR, Sun G, Macromolecules, 42(6), 1948 (2009)

[9] Moulay S, Prog. Polym. Sci, 35, 303 (2010)

[10] Piszczek K, Sterzynski T, Lukaszewicz E, Polym. Test, 22, 115 (2003)

[11] Hasan M, Banerjee AN, Lee M, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2014.04.019. (2014)

[12] Senna MMH, Hussein YA, Abdel-Moneam YK, Polym. Compos., 29, 1049 (2008)

[13] Chylinska M, Ziegler-Borowska M, Kaczmarek H, Burkowska A, Walczak M, Kosobucki P, E-Polymers, 14, 15 (2014)

[14] Sedlarik V, in: Chamy R, Rosenkranz F (Eds.), Biodegradation - Life of Science, InTech, 2013, pp. 187-204, http://www.intechopen.com/books/biodegradation-life-of-science.

[15] Chylinska M, Kaczmarek H, Thermochim. Acta, 583, 32 (2014)

[16] Gour N, Ngo KX, Vebert-Nardin C, Macromol. Mater. Eng., 299, 648 (2014)

[17] Kregiel D, Berlowska J, Mizerska U, Fortuniak W, Chojnowski J, Ambroziak W, World J. Microbiol. Biotechnol., 29, 1197 (2013)

[18] Starnes WH, Prog. Polym. Sci, 27, 2133 (2007)

[19] Endo K, Prog. Polym. Sci, 27, 2021 (2002)

[20] Saeki Y, Emura T, Prog. Polym. Sci, 27, 2055 (2002)