화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.28, 268-276, August, 2015
DOI10.1016/j.jiec.2015.03.002  Export Citation
Influence of chitosan coating on the separation performance, morphology and anti-fouling properties of the polyamide nanofiltration membranes
Ahmad Akbari†, Zahra Derikvandi, and Sayed Majid Mojallali Rostami
  • Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Islamic Republic of Iran
E-mail:
Chitosan was coated into polyamide membranes by in situ reaction of amine and hydroxyl groups of chitosan and un-reacted of acylchloride of polyamide active layer. Effect of chitosan concentration and coagulation time on the membrane chemical structure, morphology, separation performances and antifouling properties were characterized by FT-IR, SEM, AFM, cross-flow membrane module device and cetyltrimethylammonium bromide experiment. Water flux of the polyamide membranes enhanced from 32.9 to 59.6 L/m2 h and anti-fouling results proved that excellent fouling resistance. Thus, chitosan as a secondary modifier has special potential to improve the performance of polyamide membranes.
Keywords:Polyamide;Nanofiltration;Interfacial polymerization;Chitosan;Anti-fouling
  1. Kong CL, Koushima A, Kamada T, Shintani T, Kanezashi M, Yoshioka T, Tsuru T, J. Membr. Sci., 366(1-2), 382 (2011)
  2. Akbari A, Mojallali SM, Water Reused Desalination, 4, 174 (2014)
  3. Mohammadi T, Madaeni SS, Moghadam MK, Desalination, 153, 155 (2002)
  4. Li JH, Xu YY, Zhu LP, Wang JH, Du CH, J. Membr. Sci., 326(2), 659 (2009)
  5. Agenson KO, Urase T, Sep. Purif. Technol., 55(2), 147 (2007)
  6. Louie JS, Pinnau I, Ciobanu I, Ishida KP, Ng A, Reinhard M, J. Membr. Sci., 280(1-2), 762 (2006)
  7. Liu LF, Yu SC, Zhou Y, Gao CJ, J. Membr. Sci., 281(1-2), 88 (2006)
  8. An QF, Li F, Ji YL, Chen HL, J. Membr. Sci., 367(1-2), 158 (2011)
  9. Xie YJ, Yu HY, Wang SY, Xu ZK, J. Environ. Sci., 19, 1461 (2007)
  10. Wilbert MC, Pellegrino J, Zydney A, Desalination, 115(1), 15 (1998)
  11. Kim IC, Lee KH, Desalination, 192(1-3), 246 (2006)
  12. La YH, McCloskey BD, Sooriyakumaran R, Vora A, Freeman B, Nassar M, Hedrick J, Nelson A, Allen R, J. Membr. Sci., 372(1-2), 285 (2011)
  13. Kulkarni A, Mukherjee D, Gill WN, J. Membr. Sci., 114(1), 39 (1996)
  14. Belfer S, Fainshtain R, Purinson Y, Gilron J, Nystrom M, Manttari M, J. Membr. Sci., 239(1), 55 (2004)
  15. Wei XY, Wang Z, Zhang Z, Wang JX, Wang SC, J. Membr. Sci., 351(1-2), 222 (2010)
  16. VanWagner EM, Sagle AC, Sharma MM, La YH, Freeman BD, J. Membr. Sci., 367, 273 (2010)
  17. Kang GD, Yu HJ, Liu ZN, Cao YM, Desalination, 275(1-3), 252 (2011)
  18. Zou H, Jin Y, Yang J, Dai HJ, Yu XL, Xu J, Sep. Purif. Technol., 72(3), 256 (2010)
  19. Yang R, Xu JJ, Ozaydin-Ince G, Wong SY, Gleason KK, Chem. Mater., 23, 1263 (2011)
  20. Sotto A, Boromand A, Zhang RX, Luis P, Arsuaga JM, Kim J, Van der Bruggen B, J. Colloid Interface Sci., 363(2), 540 (2011)
  21. Liang S, Xiao K, Mo YH, Huang X, J. Membr. Sci., 394, 184 (2012)
  22. Lalia BS, Kochkodan V, Hashaikeh R, Hilal N, Desalination, 326, 77 (2013)
  23. Zhang Y, Su YL, Chen WJ, Peng JM, Dong YN, Jiang ZY, Liu HZ, J. Membr. Sci., 382(1-2), 300 (2011)
  24. Ji YL, An QF, Zhao Q, Chen HL, Gao CJ, J. Membr. Sci., 376(1-2), 254 (2011)
  25. Muzzarelli RAA (Ed.), Natural Chelating Polymers, Pergamon Press, New York, 1973, p. 83.
  26. Kurita K, Yoshino H, Yokota K, Ando M, Inoue S, Ishii S, Macromolecules, 25, 3786 (1992)
  27. Vasnev VA, Tarasov AI, Markova GD, Vinogradova SV, Garkusha OG, Carbohydr. Polym., 64, 184 (2006)
  28. Xu J, Feng XS, Gao CJ, J. Membr. Sci., 370(1-2), 116 (2011)
  29. Rana D, Kim Y, Matsuura T, Arafat HA, J. Membr. Sci., 367(1-2), 110 (2011)
  30. Wang YQ, Su YL, Ma XL, Sun Q, Jiang ZY, J. Membr. Sci., 283(1-2), 440 (2006)
  31. Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, Sep. Purif. Technol., 90, 69 (2012)
  32. Garcia-Aleman J, Dickson JM, J. Membr. Sci., 235(1-2), 1 (2004)
  33. Deng HY, Xu YY, Chen QC, Wei XZ, Zhu BK, J. Membr. Sci., 366(1-2), 363 (2011)
  34. Hirose M, Ito H, Kamiyama Y, J. Membr. Sci., 121(2), 209 (1996)
  35. Kim SH, Kwak EY, Suzuki T, Environ. Sci. Technol., 39, 1764 (2005)
  36. Zhang GJ, Gao X, Ji SL, Liu ZZ, J. Membr. Sci., 307(2), 151 (2008)
  37. Xu GR, Wang JN, Li CJ, Desalination, 328, 31 (2013)
  38. Mu T, Cong YH, Zhang BY, J. Appl. Polym. Sci., 129(6), 3582 (2013)
  39. Yu SC, Liu MH, Ma M, Qi M, Lu ZH, Gao CJ, J. Membr. Sci., 350(1-2), 83 (2010)
  40. Szymczyk A, Labbez C, Fievet P, Vidonne A, Foissy A, Pagetti J, Adv. Colloid Interface Sci., 103, 77 (2003)
  41. Gonzalez MI, Alvarez S, Riera FA, Alvareza R, Desalination, 228(1-3), 84 (2008)
  42. Zhang GJ, Meng H, Ji SL, Desalination, 242(1-3), 313 (2009)
  43. Zhang HT, Nie HL, Yu DG, Wu CY, Zhang YL, White CJB, Zhu LM, Desalination, 256(1-3), 141 (2010)
  44. Tang CYY, Kwon YN, Leckie JO, Desalination, 242(1-3), 149 (2009)
  45. Saha NK, Joshi SV, J. Membr. Sci., 342(1-2), 60 (2009)
  46. Kang GD, Liu M, Lin B, Cao YM, Yuan Q, Polymer, 48(5), 1165 (2007)
  47. Sagle AC, Van Wagner EM, Ju H, McCloskey BD, Freeman BD, Sharma MM, J. Membr. Sci., 340(1-2), 92 (2009)
  48. Boussu K, Van der Bruggen B, Volodin A, Van Haesendonck C, Delcour JA, Van der Meeren P, Vandecasteele C, Desalination, 191(1-3), 245 (2006)
  49. Peng JM, Su YL, Shi Q, Chen WJ, Jiang ZY, Bioresour. Technol., 102(3), 2289 (2011)