화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.28, 316-321, August, 2015
DOI10.1016/j.jiec.2015.03.009  Export Citation
A simple dispersive liquid.liquid microextraction method for determination of Ag(I) by flame atomic absorption spectrometry
Teslima Dasbası, Serife Sacmacı1, †, Ahmet Ulgen1, and Senol Kartal1
  • Department of Chemistry, Faculty of Arts and Sciences, Bozok University, 66900 Yozgat, Turkey
  • 1Department of Chemistry, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey
E-mail:
A simple and efficient dispersive liquid.liquid microextraction (DLLME) procedure was optimized for the determination of Ag(I) by flame atomic absorption spectrometry (FAAS). In this method, 8- hydroxyquinoline was used as a chelating reagent for Ag(I) and resulted complex was extracted in chloroform, while ethanol is used as disperser solvent. The effective parameters on the recovery of Ag(I), such as the pH of sample, the type and volume of extraction and disperser solvents, the amount of 8-hydroxyquinoline reagent, extraction time, the effect of temperature and interfering ions of sample solution were investigated. The calibration graph of this procedure was linear in the range of 0.02. 0.4 mg L-1 with detection limit of 2.0 mg L-1 (n = 21). The relative standard deviation (RSD) was 4% and the preconcentration factor was 65. Good recovery (%) values were obtained changing between 95 and 102%. The certified reference material (CWW-TM-D waste water) was used to verify the accuracy of the developed method (recovery, 96%). The proposed method was applied for determination of silver in different water samples, anode slime and cream samples.
Keywords:Silver;Dispersive liquid.liquid microextraction;8-Hydroxyquinoline;Flame atomic absorption spectrometry
  1. Howe PD, Dobson S, Silver and silver compounds: environmental aspects, in: Concise International Chemical Assessment Document, 44, World Health Organization, Geneva, 2002.
  2. Kocurova L, Balogh IS, Nagy L, Billes F, Simon A, Andruch V, Microchem J., 99, 514 (2011)
  3. Dittert IM, Borges DLG, Welz B, Curtius AJ, Becker-Ross H, Microchim. Acta, 167, 21 (2009)
  4. Absalan G, Akhond M, Ghanizadeh AZ, Abedi ZA, Tamami B, Sep. Purif. Technol., 56(2), 231 (2007)
  5. Katarina RK, Takayanagi T, Oshima M, Motomizu S, Anal. Chim. Acta, 558, 246 (2006)
  6. Dasbası T, Sacmacı S, Sahan S, Kartal S, Ulgen A, Talanta, 103, 1 (2013)
  7. Agency for Toxic Substances and Disease Registry, Toxicological Profile for Silver (TP_90-24), Department of Health and Human Services, Public Health Service, Atlanta, GA, USA, 1990.
  8. Eisler R, Silver Hazards to Fish, Wildlife and Invertebrates: A Synoptic Review, US Department of the Interior, National Biological Service, Washington, DC, 1996p. 44.
  9. Afzali D, Mohadesi AR, Jahromi BB, Falahnejad M, Anal. Chim. Acta, 684, 54 (2011)
  10. Mohadesi A, Taher MA, Talanta, 71, 615 (2007)
  11. Zejli H, de Cisneros JLHH, Naranjo-Rodriguez I, Temsamani KR, Talanta, 71, 1594 (2007)
  12. Javanbakht M, Divsar F, Badiei A, Fatollahi F, Khaniani Y, Ganjali MR, Norouzi P, Chaloosi M, Ziarani GM, Electrochim. Acta, 54(23), 5381 (2009)
  13. Zhang XB, Han ZX, Fang ZH, Shen GL, Yu RQ, Anal. Chim. Acta, 562, 210 (2006)
  14. Yan Z, Lu Y, Li X, Sens. Actuators B-Chem., 122, 174 (2007)
  15. Mohammadi SZ, Afzali D, Taher MA, Baghelani YM, Talanta, 80, 875 (2009)
  16. Anthemidis AN, Ioannou KIG, Talanta, 84, 1215 (2011)
  17. Soylak M, Cay RS, J. Hazard. Mater., 146(1-2), 142 (2007)
  18. Tuzen M, Soylak M, J. Hazard. Mater., 164(2-3), 1428 (2009)
  19. Christou CK, Anthemidis AN, Talanta, 78, 144 (2009)
  20. Rofouei MK, Payehghadr M, Shamsipur M, Ahmadalinezhad A, J. Hazard. Mater., 168(2-3), 1184 (2009)
  21. Araujo CST, Alves VN, Rezende HC, Coelho NMM, Microchem J., 96, 82 (2010)
  22. Ghaedi M, Shokrollahi A, Niknam K, Niknam E, Najibi A, Soylak M, J. Hazard. Mater., 168(2-3), 1022 (2009)
  23. Dadfarnia S, Shabani AMH, Gohari M, Talanta, 64, 682 (2004)
  24. Liang P, Peng L, Microchim. Acta, 168, 45 (2010)
  25. Yang GY, Fen WB, Lei C, Xiao WL, Sun HD, J. Hazard. Mater., 162(1), 44 (2009)
  26. Liang P, Zhang L, Zhao E, Talanta, 82, 993 (2010)
  27. Ashkenani H, Taher MA, Microchem J., 103, 185 (2012)
  28. Itagaki T, Ashino T, Takada K, Fresenius J. Anal. Chem., 368, 344 (2000)
  29. Kirkbright GF, Xing ZL, Analyst, 107, 617 (1982)
  30. Hill AA, Lipert RJ, Porter MD, Talanta, 80, 1606 (2010)
  31. Wen X, Kong L, Chen M, Deng Q, Zhao X, Guo J, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 97, 782 (2012)
  32. Shabazi Z, Dadfarnia S, Shabani AMH, Jafari AA, J. Anal. Chem., 63, 446 (2008)
  33. Ghaedi M, Daneshfar A, Shokrollahi A, Ghaedi H, Pili FA, Ann. Chim., 97, 971 (2007)
  34. Karbasi MH, Jahanparast B, Shamsipur M, Hassan J, J. Hazard. Mater., 170(1), 151 (2009)
  35. Hirayama N, Deguchi M, Kawasumi H, Honjo T, Talanta, 65, 255 (2005)
  36. Tavallali H, Yazdandoust S, Yazdandoust M, Clean Soil Air Water, 38, 242 (2010)
  37. Ortet O, Paiva AP, Sep. Sci. Technol., 45(8), 1130 (2010)
  38. Mohamadi M, Mostafavi A, Talanta, 81, 309 (2010)
  39. Bertelli D, Papotti G, Lolli M, Sabatini AG, Plessi M, Food Chem., 108, 297 (2008)
  40. Liu HG, Dasgupta PK, Anal. Chem., 68, 1817 (1996)
  41. Jeannot MA, Cantwell FF, Anal. Chem., 69, 235 (1997)
  42. Ahmadi F, Assadi Y, Hosseini SMRM, Rezaee M, J. Chromatogr. A, 1101, 307 (2006)
  43. Jeannot MA, Cantwell FF, Anal. Chem., 68, 2236 (1996)
  44. Xia L, Hu B, Jiang Z, Wu Y, Liang Y, Anal. Chem., 76, 2910 (2004)
  45. Arthur CL, Pawliszyn J, Anal. Chem., 62, 2145 (1990)
  46. Hall BJ, Brodbelt JS, J. Chromatogr. A, 777, 275 (1997)
  47. Ibanez E, Lopez-Sebastian S, Ramos E, Tabera J, Reglero G, Food Chem., 63, 281 (1998)
  48. Ghiasvand AR, Shadabi S, Mohagheghzadeh E, Hashemi P, Talanta, 66, 912 (2005)
  49. Igarashi S, Ide N, Takagai Y, Anal. Chim. Acta, 424, 263 (2000)
  50. Arain MS, Arain SA, Kazi TG, Afridi HI, Naeemulllah JA, Arain SS, Brahman KD, Mughal MA, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 137, 877 (2015)
  51. Naeemullah, Kazi TG, Tuzen M, Afridi HI, Citak D, Anal. Chim. Acta, 812, 59 (2014)
  52. Sacmacı S, Kartal S, Dural S, J. Braz. Chem. Soc., 23, 1033 (2012)
  53. Ozdemir C, Sacmacı S, Kartal S, Sacmacı M, J. Ind. Eng. Chem., 20(6), 4059 (2014)
  54. Lopez-Garcia I, Rivas RE, Hernandez-Cordoba M, Anal. Bioanal. Chem., 396, 3097 (2010)
  55. Elci L, Kartal S, Ulgen A, Dogan M, Dogan P, Turk. J. Chem., 14, 294 (1990)
  56. Phillips JP, Chem. Rev., 56, 271 (1956)
  57. Block BP, Bailar JC, Pearce DW, J. Am. Chem. Soc., 73, 4971 (1951)