화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.29, 359-365, September, 2015
DOI10.1016/j.jiec.2015.04.015  Export Citation
An efficient solid base catalyst from coal combustion fly ash for green synthesis of dibenzylideneacetone
Nurul A. Mazumder, and Ruma Rano†
  • Department of Chemistry, National Institute of Technology, Silchar 788010, India
E-mail:
The objective of the investigation was to evaluate the catalytic efficiency of a solid base catalyst (SBC) derived from coal combustion fly ash to synthesize dibenzylideneacetone (DBA, 94% yield). The catalyst was produced using potassium hydroxide (30 wt.%) on thermally activated F-type fly ash. The physico-chemical, mineralogical and morphological characterization of the fly ash and catalyst were performed using XRF, FT-IR, BET surface area analyser, XRD and SEM-EDS. The results of such analysis revealed that the catalyst obtained was associated with strong basic hydroxyl (-OH) sites that were highly suited to produce DBA by crossed aldol condensation reaction.
Keywords:Solid base catalyst;Dibenzylideneacetone;F-type fly ash;Crossed aldol condensation
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