p-Sulfonatothiacalix[6]arene-impregnated resins for the sorption of platinum group metals and effective separation of palladium from automotive catalyst residue

Muniyappan Rajiv Gandhi; Manabu Yamada; Yoshihiko Kondo; Atsushi Shibayama; Fumio Hamada

Journal of Industrial and Engineering Chemistry, Vol.30, 20-28, October, 2015

DOI10.1016/j.jiec.2015.04.024 Export Citation

p-Sulfonatothiacalix[6]arene-impregnated resins for the sorption of platinum group metals and effective separation of palladium from automotive catalyst residue

Muniyappan Rajiv Gandhi, Manabu Yamada^†, Yoshihiko Kondo¹, Atsushi Shibayama², and Fumio Hamada³

Research Center for Engineering Science, Graduate School of Engineering and Resource Science, Akita University, 1-1 Tegatagakuen-machi, Akita 010-8502, Japan
¹Department of Life Science, Graduate School of Engineering and Resource Science, Akita University, 1-1 Tegatagakuen-machi, Akita 010-8502, Japan
²Faculty of International Resource Sciences, Akita University, 1-1 Tegatagakuen-machi, Akita 010-8502, Japan
³Department of Applied Chemistry, Graduate School of Engineering and Resource Science, Akita University, 1-1 Tegatagakuen-machi, Akita 010-8502, Japan

E-mail:

p-Sulfonatothiacalix[6]arene was impregnated onto commercial polymeric resins. The platinum group metals sorption experiments were carried and maximum PGM sorption was observed at pH 4 in 180 min. The 1-loaded IRA-400, IRA-411, and XAD-7 showed Pd SCs of 279, 265, and 135 mg/g, respectively. The PGM SCs of 1-loaded IRA-400, IRA-411 are found to be Pd > Pt > Rh. All the impregnated resins followed Freundlich isotherm and Pd sorption was exothermic. The kinetic studies demonstrate that Pd sorption follows pseudo-second order and intraparticle diffusion models. 1-Loaded XAD-7 selectively adsorbs of Pd ions from an automotive catalyst residue leached solution.

Keywords:Polymeric resins;p-Sulfonatothiacalix[6]arene;Sorption;Palladium;Automotive catalyst residue

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[2] Matsumiya H, Ishida T, Iki N, Miyano S, Anal. Chim. Acta, 478, 163 (2003)

[3] Wu M, Yuan D, Han L, Wu B, Xu Y, Hong M, Eur. J. Inorg. Chem., 2006, 526 (2006)

[4] Chen B, Yuan D, Wu M, Jiang F, Hong M, Z. Anorg. Allg. Chem., 635, 1669 (2009)

[5] Matsumiya H, Masai H, Terazono Y, Iki N, Miyano S, Bull. Chem. Soc. Jpn., 76, 133 (2003)

[6] Jin T, Fujii F, Sakata H, Tamura M, Chem. Commun., 4300 (2005)

[7] Shinkai S, Mori S, Tsubaki T, Sone T, Manabe O, Tetrahedron Lett., 25, 5315 (1984)

[8] Shinkai S, Kawaguchi H, Manabe O, J. Polym. Sci. C: Polym. Lett., 26, 391 (1988)

[9] Atwood JL, Hamada F, Robinson KD, Orr GW, Vincent RL, Nature, 349, 683 (1991)

[10] Orr GW, Barbour LJ, Atwood JL, Science, 285, 1049 (1999)

[11] Dargarno SJ, Raston CL, J. Chem. Soc.-Dalton Trans., 287 (2003)

[12] Dargarno SJ, Fisher J, Raston CL, Chem.-Eur. J., 12, 2772 (2006)

[13] Smith CB, Barbour LJ, Makha M, Raston CL, Sobolev AN, Chem. Commun., 950 (2006)

[14] Iki N, Fujimoto T, Miyano S, Chem. Lett., 27, 625 (1998)

[15] Iki N, Hiro-oka S, Nakamura M, Tanaka T, Hoshino H, Eur. J. Inorg. Chem., 2012, 3541 (2012)

[16] Iki N, Suzuki T, Koyama K, Kabuto C, Miyano S, Org. Lett., 4, 509 (2002)

[17] Yamada M, Kondo Y, Akimoto K, Kabuto C, Hamada F, New J. Chem., 31, 1874 (2007)

[18] Yamada M, Hamada F, Cryst. Eng. Commun., 15, 5703 (2013)

[19] Yamada M, Kondo Y, Hamada F, Int. J. Soc. Mater. Eng. Res., 15, 50 (2008)

[20] Yamada M, Kondo Y, Hamada F, Tetrahedron Lett., 49, 1790 (2008)

[21] Iki N, Fujimoto T, Shindo T, Koyama K, Miyano S, Chem. Lett., 28, 777 (1999)

[22] Hu XJ, Li YS, Wang Y, Li XX, Li HY, Liu X, Zhang P, Desalination, 259(1-3), 76 (2010)

[23] Matsumiya H, Yasuno S, Iki N, Miyano S, J. Chromatogr. A, 1090, 197 (2005)

[24] Gandhi MR, Yamada M, Kondo Y, Sato R, Hamada F, Ind. Eng. Chem. Res., 53(7), 2559 (2014)

[25] Kondo Y, Shibayama A, Hamada F, Yamada M, Akama M, Imai T, U.S. Patent No. 8038969, 2011.

[26] Hamada F, Li C, Kondo Y, U.S. Patent No. 0247459, 2011.

[27] Kolliopoulos G, Balomenos E, Giannopoulou I, Yakoumis I, Panias D, Open Access Libr. J., 1, e736 (2014)

[28] Hageluken C, Platinum Met. Rev., 56, 29 (2012)

[29] Awual MR, Hasan MM, J. Ind. Eng. Chem., 21, 507 (2015)