Synthesis and surface modification of hybrid multiblock gold.nickel.polypyrrole nanorods by poly(fluorene) and their optical properties

Seung Hyun Kim; Bal Sydulu Singu; Kuk Ro Yoon

Journal of Industrial and Engineering Chemistry, Vol.30, 174-182, October, 2015

DOI10.1016/j.jiec.2015.05.019 Export Citation

Synthesis and surface modification of hybrid multiblock gold.nickel.polypyrrole nanorods by poly(fluorene) and their optical properties

Seung Hyun Kim, Bal Sydulu Singu, and Kuk Ro Yoon^†

Organic Nanomaterials Lab, Department of Chemistry, Hannam University, Daejeon 305-811, Republic of Korea

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We have demonstrated that hybrid multiblock nanorods (MBNs) consisting of gold, nickel, and polypyrrole were prepared by electrochemical deposition method using anodized aluminum oxide as a template. Thiol substituted poly(fluorene) was synthesized through Ni(0)-mediated polymerization. Thiol substituted poly(fluorene) was used for the surface modification of MBNs. The as-synthesized thiol substituted poly(fluorene) and surface modified MBNs were characterized by NMR, SEM, AFM, TEM, TGA, XRD, GPC and XPS. Optical properties of the prepared materials were investigated via UV.vis Spectroscopy and photoluminescence spectroscopy. The poly(fluorene) and surface modified MBNs were showing fluorescence decay life time of 3.47 and 2.77 ns, respectively.

Keywords:Poly(fluorene);Gold;Polypyrrole;Nickel;Nanorods

[References]

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Bansal AK, Ruseckas A, Shaw PE, Samuel IDW, J. Phys. Chem. C, 114, 17864 (2010)
Zhang W, Chen Y, Gan L, Qing J, Zhou X, Huang Y, Yang Y, Zhang Y, Ou J, Chen X, Zhang MQ, J. Phys. Chem. Solids, 75, 1340 (2014)
Sugikawa K, Nagata S, Furukawa Y, Kokado K, Sada K, Chem. Mater., 25, 2565 (2013)
Senthilkumar T, Asha SK, Macromolecules, 46(6), 2159 (2013)
Zhang Y, Chu W, Foroushani AD, Wang H, Li D, Liu J, Barrow CJ, Wang X, Yang W, Materials, 7, 5169 (2014)
Gence L, Callegari V, Champagne SD, Duvail JL, J. Phys. Chem. C, 118, 9385 (2014)
Callegari V, Demoustier-Champagne S, Macromol. Rapid Commun., 32(1), 25 (2011)
Callegari V, Gence L, Melinte S, Demoustier-Champagne SD, Chem. Mater., 21, 4241 (2009)
Sahu D, Chu HC, Yang PJ, Lin HC, Macromol. Chem. Phys., 213, 1550 (2012)
Nakamura M, Yamabuki K, Oishi T, Onimura K, J. Polym. Sci. A: Polym. Chem., 51(23), 4945 (2013)
Zeysing B, Gosch C, Terfort A, Org. Lett., 2, 1843 (2000)
Klarner G, Lee JI, Lee VY, Chan E, Chen JP, Nelson A, Markiewicz D, Siemens R, Scott JC, Miller RD, Chem. Mater., 11, 1800 (1999)
Marsitzky D, Klapper M, Mullen K, Macromolecules, 32(25), 8685 (1999)
Joint Committee on Powder Diffraction Standards, Diffraction Data File, JCPDS International Center for Diffraction Data, Swarthmore, PA, 1991.
Palaniappan S, Sydulu SB, Srinivas P, J. Appl. Polym. Sci., 115(3), 1695 (2010)
Vericat C, Vela ME, Andreasen G, Salvarezza RC, Vazquez L, Martin-Gago JA, Langmuir, 17(16), 4919 (2001)
Fratoddi I, Venditti I, Battocchio C, Polzonetti G, Bondino F, Malvestuto M, Piscopiello E, Tapfer L, Russo MV, J. Phys. Chem. C, 115, 15198 (2011)
Carbas BB, Asil D, Friend RH, Onal AM, Org. Electron., 15, 500 (2014)
Bliznyuk VN, Carter SA, Scott JC, Klarner G, Miller RD, Miller DC, Macromolecules, 32(2), 361 (1999)
Neher D, Macromol. Rapid Commun., 22, 1365 (2001)
Chen H, Zeng G, Wang Z, Zhang X, Peng ML, Wu LZ, Tung CH, Chem. Mater., 17, 6679 (2005)
Joly S, Kane R, Radzilowski L, Wang T, Wu A, Cohen RE, Thomas EL, Rubner MF, Langmuir, 16, 1354 (1999)

[Referenced By]

[1] Marques AT, Burrows HD, de Melo JSS, Valente AJM, Justino LLG, Scherf U, Fron E, Rocha S, Hofkens J, Snedden EW, Monkman AP, J. Phys. Chem. B, 116(25), 7548 (2012)

[2] Bansal AK, Ruseckas A, Shaw PE, Samuel IDW, J. Phys. Chem. C, 114, 17864 (2010)

[3] Zhang W, Chen Y, Gan L, Qing J, Zhou X, Huang Y, Yang Y, Zhang Y, Ou J, Chen X, Zhang MQ, J. Phys. Chem. Solids, 75, 1340 (2014)

[4] Sugikawa K, Nagata S, Furukawa Y, Kokado K, Sada K, Chem. Mater., 25, 2565 (2013)

[5] Senthilkumar T, Asha SK, Macromolecules, 46(6), 2159 (2013)

[6] Zhang Y, Chu W, Foroushani AD, Wang H, Li D, Liu J, Barrow CJ, Wang X, Yang W, Materials, 7, 5169 (2014)

[7] Gence L, Callegari V, Champagne SD, Duvail JL, J. Phys. Chem. C, 118, 9385 (2014)

[8] Callegari V, Demoustier-Champagne S, Macromol. Rapid Commun., 32(1), 25 (2011)

[9] Callegari V, Gence L, Melinte S, Demoustier-Champagne SD, Chem. Mater., 21, 4241 (2009)

[10] Sahu D, Chu HC, Yang PJ, Lin HC, Macromol. Chem. Phys., 213, 1550 (2012)

[11] Nakamura M, Yamabuki K, Oishi T, Onimura K, J. Polym. Sci. A: Polym. Chem., 51(23), 4945 (2013)

[12] Zeysing B, Gosch C, Terfort A, Org. Lett., 2, 1843 (2000)

[13] Klarner G, Lee JI, Lee VY, Chan E, Chen JP, Nelson A, Markiewicz D, Siemens R, Scott JC, Miller RD, Chem. Mater., 11, 1800 (1999)

[14] Marsitzky D, Klapper M, Mullen K, Macromolecules, 32(25), 8685 (1999)

[15] Joint Committee on Powder Diffraction Standards, Diffraction Data File, JCPDS International Center for Diffraction Data, Swarthmore, PA, 1991.

[16] Palaniappan S, Sydulu SB, Srinivas P, J. Appl. Polym. Sci., 115(3), 1695 (2010)

[17] Vericat C, Vela ME, Andreasen G, Salvarezza RC, Vazquez L, Martin-Gago JA, Langmuir, 17(16), 4919 (2001)

[18] Fratoddi I, Venditti I, Battocchio C, Polzonetti G, Bondino F, Malvestuto M, Piscopiello E, Tapfer L, Russo MV, J. Phys. Chem. C, 115, 15198 (2011)

[19] Carbas BB, Asil D, Friend RH, Onal AM, Org. Electron., 15, 500 (2014)

[20] Bliznyuk VN, Carter SA, Scott JC, Klarner G, Miller RD, Miller DC, Macromolecules, 32(2), 361 (1999)

[21] Neher D, Macromol. Rapid Commun., 22, 1365 (2001)

[22] Chen H, Zeng G, Wang Z, Zhang X, Peng ML, Wu LZ, Tung CH, Chem. Mater., 17, 6679 (2005)

[23] Joly S, Kane R, Radzilowski L, Wang T, Wu A, Cohen RE, Thomas EL, Rubner MF, Langmuir, 16, 1354 (1999)