화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.30, 225-233, October, 2015
DOI10.1016/j.jiec.2015.05.026  Export Citation
Improved performance of cerium conversion coatings on steel with zinc phosphate post-treatment
B. Ramezanzadeh†, H. Vakili, and R. Amini
  • Department of Surface Coating and Corrosion, Institute for Color Science and Technology, No. 59,Vafamanesh St, HosainabadSq, Lavizan, Tehran, Iran
E-mail:
The steel samples were pre-treated by cerium conversion layer. Then, zinc phosphate conversion coating was used as sealing agent for the cerium conversion layer to enhance its corrosion resistance. The corrosion performance and surface characteristics of the samples were characterized by electrochemical impedance spectroscopy, scanning electron microscope and X-ray photoelectron spectroscopy. Results revealed that the post-treatment of the cerium conversion coating by phosphate coating significantly increased its corrosion resistance. A denser conversion layer with less cracks were precipitated on the steel surface after post-treatment by zinc phosphate. The surface free energy was significantly increased after post-treatment by zinc phosphate.
Keywords:Cerium;Zinc phosphate;Conversion coating;X-ray photoelectron spectroscopy
  1. Sandu AV, Coddet C, Bejinariu C, Rev. Chim., 63(4), 401 (2012)
  2. Ramezanzadeh B, Attar MM, Corrosion, 69(8), 793 (2013)
  3. Neri W, Introduzione alla Verniciatura delle superfici metalliche, third ed., Tecniche Nuove, Milan, 1990.
  4. Xinweng Y, Chunan C, Zhiming Y, Derui Z, Zhongda Y, Corrosion Sci., 43, 1283 (2001)
  5. Tang N, van Ooij WJ, Grecki G, Prog. Org. Coat., 30, 255 (1997)
  6. Zhanga X, van den Bos C, Sloof WG, Hovestad A, Terryn H, de Wit JHW, Surf. Coat. Technol., 199, 92 (2005)
  7. Zhang X, Sloof WG, Hovestad A, van Westing EPM, Terryn H, de Wit JHW, Surf. Coat. Technol., 197, 168 (2005)
  8. Zhang W, Li JQ, Wu YS, Xu JT, Chen K, Surf. Eng., 19, 224 (2002)
  9. Hinton BRW, Arnott DR, Ryan NE, Mater. Forum, 9, 162 (1986)
  10. Golru SS, Attar MM, Ramezanzadeh B, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.09.036. (2014)
  11. Ramezanzadeh B, Attar MM, Farzam M, Surf. Coat. Technol., 205(3), 874 (2010)
  12. Ryu HS, Ahn HJ, Kim KW, Ahn JH, Cho KK, Nam TH, Electrochim. Acta, 52(4), 1563 (2006)
  13. Tsai CY, Liu JS, Chen PL, Lin CS, Surf. Coat. Technol., 205, 5124 (2011)
  14. Tsai CY, Liu JS, Chen PL, Lin CS, Corrosion Sci., 52, 3385 (2010)
  15. Tsai CY, Liu JS, Chen PL, Lin CS, Corrosion Sci., 52, 3907 (2010)
  16. Jiang L, Wolpers M, Volovitch P, Ogle K, Corrosion Sci., 55, 76 (2012)
  17. Hao Y, Liu F, Han E, Anjum S, Xu G, Corrosion Sci., 69, 77 (2013)
  18. Magalhaes AAO, Margarit ICP, Mattos OR, J. Electroanal. Chem., 572(2), 433 (2004)
  19. Ghanbari A, Attar MM, Surf. Coat. Technol., 246, 26 (2014)
  20. Ferreira MGS, Duarte RG, Montemor MF, Simoes AMP, Electrochim. Acta, 49(17-18), 2927 (2004)
  21. Trabelsi W, Cecilio P, Ferreira MGS, Montemor MF, Prog. Org. Coat., 54, 276 (2005)
  22. Trabelsi W, Triki E, Dhouibi L, Ferreira MGS, Zheludkevich ML, Montemor MF, Surf. Coat. Technol., 200, 4240 (2006)
  23. Garcia-Heras M, Jimenez-Morales A, Casal B, Galvan JC, Radzki S, Villegas MA, J. Alloy. Compd., 380, 219 (2004)
  24. Shin AS, Shon MY, J. Ind. Eng. Chem., 16(6), 884 (2010)
  25. Min J, Park JH, Sohn HK, Park JM, J. Ind. Eng. Chem., 18(2), 655 (2012)
  26. Oh JE, Kim YH, J. Ind. Eng. Chem., 18(3), 1082 (2012)
  27. Ghanbari A, Attar MM, Appl. Surf. Sci., 316(15), 429 (2014)
  28. Ramezanzadeh B, Vakili H, Amini R, Appl. Surf. Sci., 327, 174 (2015)
  29. Su HY, Lin CS, Corrosion Sci., 83, 137 (2014)
  30. Phuong NV, Lee KH, Chang D, Moon S, Corrosion Sci., 74, 314 (2013)
  31. Johnson BY, Edington J, O’Keefe MJ, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 361, 225 (2003)
  32. Heller DK, Fahrenholtz WG, O'Keefe MJ, J. Electrochem. Soc., 156(11), C400 (2009)
  33. Heller DK, Fahrenholtz WG, O’Keefe MJ, Mater. Charact., N62(11), 1071 (2011)
  34. Dong S, Xingguo F, Mingren S, Xinxin M, Guangze T, J. Rare Earth, 30(4), 383 (2012)
  35. Jegdic BV, Zivkovic LS, Popic JP, Bajat JB, Miskovic-Stankovic VB, J. Serb. Chem. Soc., 78(7), 997 (2013)
  36. Rezaee N, Attar MM, Ramezanzadeh B, Surf. Coat. Technol., 236, 361 (2013)
  37. Hassena S, Bousselmi L, Bercot P, Rezrazi EM, Triki E, Rare Met., 30(4), 368 (2011)
  38. Davenport AJ, Isaac HS, Kendig MW, Corrosion Sci., 32(5-6), 653 (1991)
  39. Aldykiewicz AJ, Davenport AJ, Isaacs HS, J. Electrochem. Soc., 143(1), 147 (1996)
  40. Hassen SB, Bousselmi L, Bercot P, Rezrazi EM, Triki E, Rare Met., 28(3), 277 (2009)
  41. Montemor MF, Simoes AM, Ferreira MGS, Carmezim MJ, Appl. Surf. Sci., 254(6), 1806 (2008)
  42. Montemor MF, Simoes AM, Carmezim MJ, Appl. Surf. Sci., 253(16), 6922 (2007)
  43. Yu X, Li G, J. Alloy. Compd., 364, 193 (2004)
  44. Yu P, Hayes SA, O'Keefe TJ, O'Keefe MJ, Stoffer JO, J. Electrochem. Soc., 153(1), C74 (2006)
  45. Song Y, Shan D, Chen R, Zhang F, Han EH, Surf. Coat. Technol., 203, 1107 (2009)
  46. Maeda S, Yamamoto M, Prog. Org. Coat., 33, 83 (1998)
  47. Li D, Neumann AW, J. Colloid Interface Sci., 137, 304 (1992)
  48. Hirschorn B, Orazem ME, Tribollet B, Vivier V, Frateur I, Musiani M, Electrochim. Acta, 55(21), 6218 (2010)
  49. Su HY, Lin CS, Corrosion Sci., 83, 137 (2014)