Adsorption behaviour of 2-mercaptobenzamide modified itaconic acid-grafted-magnetite nanocellulose composite for cadmium(II) from aqueous solutions

T.S. Anirudhan; F. Shainy

Journal of Industrial and Engineering Chemistry, Vol.32, 157-166, December, 2015

DOI10.1016/j.jiec.2015.08.011 Export Citation

Adsorption behaviour of 2-mercaptobenzamide modified itaconic acid-grafted-magnetite nanocellulose composite for cadmium(II) from aqueous solutions

T.S. Anirudhan^†, and F. Shainy

Department of Chemistry, School of Physical and Mathematical Sciences, University of Kerala, Kariavattom, Trivandrum 695 581, India

E-mail:

In the present study, a cellulose based adsorbent, P(MB-IA)-g-MNCC was synthesized by graft copolymerization of itaconic acid onto MNCC using EGDMA as crosslinking agent and K2S2O8 as free radical initiator. P(MB-IA)-g-MNCC was characterized by FTIR, XRD, SEM, TG and VSM. Cd(II) adsorption occurs maximum at pH 6.0. Kinetic and isotherm data were described using pseudo-second-order kinetic model and Sips isotherm model, respectively. Adsorbent dosage of 2.0 g/L was sufficient for the complete removal of Cd(II) ions from aqueous solutions. The maximum adsorption capacity of P(MB-IA)-g-MNCC was found to be 262.27 mg/g. Spent adsorbent was effectively regenerated using 0.1 M HCl.

Keywords:Magnetite nanocellulose;Graft co-polymerization;2-Mercaptobenzamide;Cadmium(II);Adsorption

[References]

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Semerjian L, J. Hazard. Mater., 173(1-3), 236 (2010)
Tajar AF, Kaghazchi T, Soleimani M, J. Hazard. Mater., 165(1-3), 1159 (2009)
Balkaya N, Cesur H, Chem. Eng. J., 140(1-3), 247 (2008)
Atia AA, Hydrometallurgy, 80, 13 (2005)
Lagadic IL, Mitchell MK, Payne BD, Environ. Sci. Technol., 35, 984 (2001)
Sheng GD, Wang SW, Hu J, Lu Y, Li JX, Dong YH, Wang XK, Colloids Surf. A: Physicochem. Eng. Asp., 339, 159 (2009)
Justi KC, Favere VT, Laranjeira MCM, Neves A, Peralta RA, J. Colloid Interface Sci., 291(2), 369 (2005)
Young RJ, Eichhorn SJ, Polymer, 48(1), 2 (2007)
Anirudhan TS, Rejeena SR, J. Colloid Interface Sci., 381, 125 (2012)
Dias AMGC, Hussain A, Marcos AS, Rouque ACA, Biotechnol. Adv., 29, 142 (2011)
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Anirudhan TS, Rejeena SR, Carbohydr. Polym., 93, 518 (2013)
Tolaymat I, 1,4-Benzothiazepines,3-hydroxy-benzo[b]thiophene-2-carboxa-mides and Benzothieno[2,3-e][1,3]oxazines Derived From Thiosalicylic Acid, (Ph.D. thesis), University of Hamburg, 2009.
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Stewart BA, Whitfield CJ, Soil Sci. Soc. Am. Proc., 29, 752 (1965)
Anirudhan TS, Tharun AR, Chem. Eng. J., 181-182, 761 (2012)
Noisuwan A, Hemar Y, Wilkinson B, Boronlund JE, Carbohydr. Polym., 84, 247 (2011)
Anirudhan TS, Rejeena SR, Binusree J, J. Chem. Eng. Data, 58(5), 1329 (2013)
Gao M, Dai Q, Chin. J. Process Eng., 6, 242 (2006)
Luo C, Wei RY, Guo D, Zhang SF, Yan SQ, Chem. Eng. J., 225, 406 (2013)
Anirudhan TS, Deepa JR, Binusreejayan, Chem. Eng. J., 273, 390 (2015)
Kumar U, Bandyopadhyay M, Bioresour. Technol., 97(1), 104 (2006)
Gurgel LVA, Freitas RP, Gil LF, Carbohydr. Polym., 74, 922 (2008)
Hu X, Zhao M, Song G, Huang H, Environ. Technol., 32, 739 (2011)
Panda L, Das B, Rao DS, Mishra BK, J. Hazard. Mater., 192(2), 822 (2011)
Junior OK, Gurgel LVA, Freitas RP, Carbohydr. Polym., 77, 643 (2009)
Najafi M, Yousefi Y, Rafati AA, Sep. Purif. Technol., 85, 193 (2012)
Belela Z, Jeguirim M, Belhachemi M, Addoun F, Teouve G, Environ. Chem. Lett., 9, 65 (2011)
Anabela L, Rosalina S, Adsorption, 11, 167 (2005)
Li C, Duan HD, Wang XJ, Meng X, Qin DW, Chem. Eng. J., 262, 250 (2015)

[Referenced By]

[1] Zhao X, Jiang T, Du B, Chemosphere, 99, 41 (2014)

[2] Chand P, Shil AK, Sharma M, Pakade YB, Int. Biodeterior. Biodegrad., 90, 8 (2014)

[3] Ihsanullah, Al-Khaldi FA, Abusharkh B, Khaled M, Atieh MA, Nasser MS, Iaoui T, Saleh TA, Agarwal S, Tyagi I, Gupta VK, J. Mol. Liq., 204, 255 (2015)

[4] saif MMS, kumar NS, Prasad MNV, Colloids Surf. B: Biointerfaces, 94, 73 (2012)

[5] Romero-Gonzalez ME, Williams CJ, Gardiner PHE, Environ. Sci. Technol., 35, 3025 (2001)

[6] Semerjian L, J. Hazard. Mater., 173(1-3), 236 (2010)

[7] Tajar AF, Kaghazchi T, Soleimani M, J. Hazard. Mater., 165(1-3), 1159 (2009)

[8] Balkaya N, Cesur H, Chem. Eng. J., 140(1-3), 247 (2008)

[9] Atia AA, Hydrometallurgy, 80, 13 (2005)

[10] Lagadic IL, Mitchell MK, Payne BD, Environ. Sci. Technol., 35, 984 (2001)

[11] Sheng GD, Wang SW, Hu J, Lu Y, Li JX, Dong YH, Wang XK, Colloids Surf. A: Physicochem. Eng. Asp., 339, 159 (2009)

[12] Justi KC, Favere VT, Laranjeira MCM, Neves A, Peralta RA, J. Colloid Interface Sci., 291(2), 369 (2005)

[13] Young RJ, Eichhorn SJ, Polymer, 48(1), 2 (2007)

[14] Anirudhan TS, Rejeena SR, J. Colloid Interface Sci., 381, 125 (2012)

[15] Dias AMGC, Hussain A, Marcos AS, Rouque ACA, Biotechnol. Adv., 29, 142 (2011)

[16] Anirudhan TS, Rejeena SR, Tharun AR, Colloids Surf. B: Biointerfaces, 93, 49 (2012)

[17] Li J, Brill TB, J. Phys. Chem. A, 105(48), 10839 (2001)

[18] Fontanile YGM, Organic and Physical Chemistry of Polymers, John Wiley & Sons, Hoboken, NJ, 2008.

[19] Ge F, Li MM, Ye H, Zhao BX, J. Hazard. Mater., 211, 366 (2012)

[20] Zargoosh K, Abedini H, Abdolmaleki A, Molavian MR, Ind. Eng. Chem. Res., 52(42), 14944 (2013)

[21] Yavuz E, Senkal BF, Bicak N, React. Funct. Polym., 65(1-2), 121 (2005)

[22] Anirudhan TS, Rejeena SR, Carbohydr. Polym., 93, 518 (2013)

[23] Tolaymat I, 1,4-Benzothiazepines,3-hydroxy-benzo[b]thiophene-2-carboxa-mides and Benzothieno[2,3-e][1,3]oxazines Derived From Thiosalicylic Acid, (Ph.D. thesis), University of Hamburg, 2009.

[24] Das MS, Trace Analysis and Technological Development, Wiley Eastern Ltd., New Delhi, 1983p. 495.

[25] Stewart BA, Whitfield CJ, Soil Sci. Soc. Am. Proc., 29, 752 (1965)

[26] Anirudhan TS, Tharun AR, Chem. Eng. J., 181-182, 761 (2012)

[27] Noisuwan A, Hemar Y, Wilkinson B, Boronlund JE, Carbohydr. Polym., 84, 247 (2011)

[28] Anirudhan TS, Rejeena SR, Binusree J, J. Chem. Eng. Data, 58(5), 1329 (2013)

[29] Gao M, Dai Q, Chin. J. Process Eng., 6, 242 (2006)

[30] Luo C, Wei RY, Guo D, Zhang SF, Yan SQ, Chem. Eng. J., 225, 406 (2013)

[31] Anirudhan TS, Deepa JR, Binusreejayan, Chem. Eng. J., 273, 390 (2015)

[32] Kumar U, Bandyopadhyay M, Bioresour. Technol., 97(1), 104 (2006)

[33] Gurgel LVA, Freitas RP, Gil LF, Carbohydr. Polym., 74, 922 (2008)

[34] Hu X, Zhao M, Song G, Huang H, Environ. Technol., 32, 739 (2011)

[35] Panda L, Das B, Rao DS, Mishra BK, J. Hazard. Mater., 192(2), 822 (2011)

[36] Junior OK, Gurgel LVA, Freitas RP, Carbohydr. Polym., 77, 643 (2009)

[37] Najafi M, Yousefi Y, Rafati AA, Sep. Purif. Technol., 85, 193 (2012)

[38] Belela Z, Jeguirim M, Belhachemi M, Addoun F, Teouve G, Environ. Chem. Lett., 9, 65 (2011)

[39] Anabela L, Rosalina S, Adsorption, 11, 167 (2005)

[40] Li C, Duan HD, Wang XJ, Meng X, Qin DW, Chem. Eng. J., 262, 250 (2015)