화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.32, 218-224, December, 2015
DOI10.1016/j.jiec.2015.08.019  Export Citation
Pd(PrSO3)2@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water
Sadegh Rostamnia†, Turaj Rahmani, and Hongchuan Xin1, †
  • Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box. 55181-83111, Maragheh, Iran
  • 1Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China
E-mail:,
A series of ordered mesoporous organic.inorganic hybrid material are designed by using the SO3Hfunctionalized SBA-15 [(PdX2@SBA-15/SO3H or Pd(PrSO3)2@SBA-15) and (Pd-NPs@SBA-15/SO3H or Pd-NPs(PrSO3)@SBA-15)] as solid supports for palladium ions. Among them, the encapsulated Pd(MeCN)2Cl2 into the SBA-15/SO3H and Pd-NPs@SBA-15/SO3H exhibit higher activity and selectivity toward Suzuki cross-coupling reaction in aerobic condition and water/DMF solvent. These heteroge-neous palladium precatalysts could be separated from the reaction mixture and reused at least 11 times.
Keywords:Pd(PrSO3)2@SBA-15;Pd-NPs(PrSO3)@SBA-15;Interface catalyst;Suzuki C.X activations.
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