화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.33, 316-325, January, 2016
DOI10.1016/j.jiec.2015.10.019  Export Citation
Crystallization behavior of tantalum and chlorine co-substituted hydroxyapatite nanopowders
Bahman Nasiri-Tabrizi†, Belinda Pingguan-Murphy1, Wan Jefrey Basirun2, and Saeid Baradaran3
  • Advanced Materials Research Center, Materials Engineering Department, Najafabad Branch,, Islamic Azad University, Najafabad, Iran, Korea
  • 1Department of Biomedical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 2Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 3Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia
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The crystallization behavior of tantalum and chlorine co-substituted hydroxyapatite nanopowders was examined. Results showed that combined processing by mechanical alloying and annealing is conducive to the structural changes and crystal growth. A series of nanocrystalline tantalum and chlorine cosubstituted hydroxyapatite (Ta/Cl-HA) with different dopant contents were synthesized as a result of the progressive mechanochemical reaction. During the subsequent annealing, crystallization of the asmilled powders occurred, leading to a significant increase in the fraction of crystalline phase. TEM images revealed that the crystallized and doped nanopowders composed of crystalline nanoneedles with an average size of 61 ± 26 nm.
Keywords:Crystallization;Hydroxyapatite;Co-substitution;Nanopowders;Reaction mechanism
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