화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 76-83, February, 2016
DOI10.1016/j.jiec.2015.10.037  Export Citation
Influences of zinc.metal complex on the carbon dioxide regeneration behaviors of alkanolamine absorbents
Young Ju Choi1, 2, Dharmalingam Sivanesan1, 3, Jiyeon Lee1, 3, Min Hye Youn1, 3, Ki Tae Park1, 3, Hak Joo Kim1, 3, Andrew Nirmala Grace4, †, In Ho Kim2, †, and Soon Kwan Jeong1, 3, †
  • 1Green Energy Process Laboratory, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea
  • 2Department of Chemical Engineering, Chungnam National University, 99, Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea
  • 3, Korea
  • 4Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu, India
E-mail:, ,
In this work, primary (MEA), secondary (DEA) and tertiary (MDEA) alkanolamine absorbents with a synthesized zinc.metal complex functioning as a carbonic anhydrase (CA) mimetic catalyst were applied to the absorption.desorption of carbon dioxide. Regeneration of carbon dioxide was evaluated by using a semi-batch system and the formation and extinction of bicarbonate and carbamate species were analyzed by FTIR and 13C NMR spectroscopy. The zinc.metal complex can cause the rapid conversion from bicarbonate to carbon dioxide, confirming that the regeneration rate could be increased substantially.
Keywords:CO2 regeneration;Carbonic anhydrase;Mimetic catalyst;CO2 sequestration;Alkanolamine
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