Investigation and prediction of the salting-out effect of methane in various aqueous electrolyte solutions

Kwangmin Kim; Kyeongjun Seo; Jaewon Lee; Myung-Gil Kim; Kyoung-Su Ha; Choongik Kim

Journal of Industrial and Engineering Chemistry, Vol.34, 117-121, February, 2016

DOI10.1016/j.jiec.2015.10.041 Export Citation

Investigation and prediction of the salting-out effect of methane in various aqueous electrolyte solutions

Kwangmin Kim, Kyeongjun Seo, Jaewon Lee, Myung-Gil Kim¹, Kyoung-Su Ha, and Choongik Kim^†

Department of Chemical and Biomolecular Engineering, Sogang University, 1 Shinsoo-dong, Mapo-gu, Seoul 121-742, Republic of Korea
¹Department of Chemistry, Chung-Ang University, 221 Heukseok-dong, Dongjak-gu, Seoul 156-756, Republic of Korea

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The maximum solubility of methane was determined in aqueous solution of Al2(SO4)3, MgSO4, K2SO4, Na2SO4, AlCl3, MgCl2, KCl, NaCl, MgBr2, KBr, and NaBr with various concentration (1, 3 and 5 wt%) at ambient pressure. Salting-out effect was observed in all electrolyte solutions, exhibiting lower solubility of methane compared to that in pure water. In general, electrolyte solutions comprising cations/anions with high charge valency and small ionic radius exhibited stronger salting-out effect due to large charge density of the corresponding ions. Furthermore, anions exhibited larger influence on the degree of salting-out compared to cations. Scaled particle theory was employed to corroborate the trend of the experimental solubility of methane in electrolyte solutions.

Keywords:Electrolyte;Salting-out effect;Methane solubility;Scale particle theory;Charge density

[References]

Dehghani F, Foster NR, Curr. opin. Solid State Mat. Sci., 7, 363 (2003)
Ohgaki K, Takano K, Sangawa H, Matsubara T, Nakano S, J. Chem. Eng. Jpn., 29(3), 478 (1996)
Michaels AS, Vieth WR, Barrie JA, J. Appl. Phys., 34, 1 (1963)
Tissot BP, Welte DH, Petroleum Formation and Occurrence, Springer-Verlag, 1984p. 3.
Duan CH, Luo MF, Xing XH, Bioresour. Technol., 102(15), 7349 (2011)
Phelps PA, Agarwal SK, Speitel GE, Georgiou G, Appl. Environ. Microbiol., 58, 3701 (1992)
Kunz W, Henle J, Ninham BW, Curr. Opin. Colloid Interface Sci., 9, 19 (2004)
Kiepe J, Horstmann S, Fischer K, Gmehling J, Ind. Eng. Chem. Res., 41(17), 4393 (2002)
Gorgenyi M, Dewulfb J, Langenhoveb HV, Heberger K, Chemosphere, 65, 802 (2006)
Gross PM, Chem. Rev., 13, 91 (1933)
Carvalho PJ, Pereira LMC, Goncalves NPF, Queimada AJ, Coutinho JAP, Fluid Phase Equilib., 388, 100 (2015)
Docherty H, Galindo A, Sanz E, Vega C, J. Phys. Chem. B, 111(30), 8993 (2007)
Yamamoto S, Alcauskas JB, Crozier TE, J. Chem. Eng. Data, 21, 78 (1976)
Stoessell PK, Byrne PA, Geochim. Cosmochim. Acta, 46, 1327 (1982)
Millero FJ, Huang F, Laferiere AL, Mar. Chem., 78, 217 (2002)
Pierotti RA, Chem. Rev., 76, 717 (1976)
Pierotti RA, J. Phys. Chem., 69, 281 (1965)
Masterton WL, Lee TP, J. Phys. Chem., 74, 1776 (1970)
Kiepe J, Horstmann S, Fischer K, Gmehling J, Ind. Eng. Chem. Res., 42(21), 5392 (2003)
Lee J, Yasin M, Park S, Chang IS, Ha KS, Lee EY, Lee J, Kim C, Korean J. Chem. Eng., 32(6), 1060 (2015)
Park S, Yasin M, Kim D, Park H, Kang C, Kim D, Chang I, J. Ind. Microbiol. Biotechnol., 40, 995 (2013)
Ben-Naim A, Molecular Theory of Solutions, Oxford, New York, 2006, p. 206;
Guha A, Panda D, J. Fluor. Chem., 125, 653 (2004)
Stillinger FH, J. Solut. Chem., 2, 141 (1973)
Shimizu S, Ikeguchi M, Nakamura S, Shimizu K, J. Chem. Phys., 110(6), 2971 (1999)
Graziano G, Can. J. Chem., 80, 401 (2002)
Graziano G, J. Chem. Phys., 129, 084506 (2008)
Hirschfelder JO, Curtiss CF, Bird RB, Mayer MG, Molecular Theory of Gases and Liquids, Wiley, New York, 1954, p. 168.
Graziano G, Chem. Phys. Lett., 396(4-6), 226 (2004)
Zaytsev ID, Aseyev GG, Properties of Aqueous Solutions of Electrolytes, CRC Press, 1992p. 67.
Kapustinskii A, Quart. Rev. Chem. Soc., 10, 283 (1956)
Shannon R, Acta Crystallogr. Sect. A, 32, 751 (1976)
Sorenson JM, Hura G, Glaeser RM, Head-Gordon T, J. Chem. Phys., 113(20), 9149 (2000)
Hasseine A, Meniai AH, Korichi M, Desalination, 242(1-3), 264 (2009)
Maemets V, Koppel I, J. Chem. Soc.-Faraday Trans., 94, 3261 (1998)
Claussen W, Polglase M, J. Am. Chem. Soc., 74, 4817 (1952)
Bostrom M, Ninham BW, J. Phys. Chem. B, 108(33), 12593 (2004)
Battino R, Clever HL, Chem. Rev., 66, 395 (1966)
Liu YH, Hou MQ, Yang GY, Han BX, J. Supercrit. Fluids, 56(2), 125 (2011)
Ellis A, Am. J. Sci., 257, 217 (1959)
Morrison TJ, J. Chem. Soc.-Faraday Trans., 40, 43 (1944)
Gutmann V, Pure Appl. Chem., 63, 1715 (1991)
Castrillon SRV, Giovambattista N, Aksay IA, Debenedetti PG, J. Phys. Chem. B, 113(5), 1438 (2009)
Collins KD, Biophys. J., 72, 65 (1997)

[Referenced By]

[1] Dehghani F, Foster NR, Curr. opin. Solid State Mat. Sci., 7, 363 (2003)

[2] Ohgaki K, Takano K, Sangawa H, Matsubara T, Nakano S, J. Chem. Eng. Jpn., 29(3), 478 (1996)

[3] Michaels AS, Vieth WR, Barrie JA, J. Appl. Phys., 34, 1 (1963)

[4] Tissot BP, Welte DH, Petroleum Formation and Occurrence, Springer-Verlag, 1984p. 3.

[5] Duan CH, Luo MF, Xing XH, Bioresour. Technol., 102(15), 7349 (2011)

[6] Phelps PA, Agarwal SK, Speitel GE, Georgiou G, Appl. Environ. Microbiol., 58, 3701 (1992)

[7] Kunz W, Henle J, Ninham BW, Curr. Opin. Colloid Interface Sci., 9, 19 (2004)

[8] Kiepe J, Horstmann S, Fischer K, Gmehling J, Ind. Eng. Chem. Res., 41(17), 4393 (2002)

[9] Gorgenyi M, Dewulfb J, Langenhoveb HV, Heberger K, Chemosphere, 65, 802 (2006)

[10] Gross PM, Chem. Rev., 13, 91 (1933)

[11] Carvalho PJ, Pereira LMC, Goncalves NPF, Queimada AJ, Coutinho JAP, Fluid Phase Equilib., 388, 100 (2015)

[12] Docherty H, Galindo A, Sanz E, Vega C, J. Phys. Chem. B, 111(30), 8993 (2007)

[13] Yamamoto S, Alcauskas JB, Crozier TE, J. Chem. Eng. Data, 21, 78 (1976)

[14] Stoessell PK, Byrne PA, Geochim. Cosmochim. Acta, 46, 1327 (1982)

[15] Millero FJ, Huang F, Laferiere AL, Mar. Chem., 78, 217 (2002)

[16] Pierotti RA, Chem. Rev., 76, 717 (1976)

[17] Pierotti RA, J. Phys. Chem., 69, 281 (1965)

[18] Masterton WL, Lee TP, J. Phys. Chem., 74, 1776 (1970)

[19] Kiepe J, Horstmann S, Fischer K, Gmehling J, Ind. Eng. Chem. Res., 42(21), 5392 (2003)

[20] Lee J, Yasin M, Park S, Chang IS, Ha KS, Lee EY, Lee J, Kim C, Korean J. Chem. Eng., 32(6), 1060 (2015)

[21] Park S, Yasin M, Kim D, Park H, Kang C, Kim D, Chang I, J. Ind. Microbiol. Biotechnol., 40, 995 (2013)

[22] Ben-Naim A, Molecular Theory of Solutions, Oxford, New York, 2006, p. 206;

[23] Guha A, Panda D, J. Fluor. Chem., 125, 653 (2004)

[24] Stillinger FH, J. Solut. Chem., 2, 141 (1973)

[25] Shimizu S, Ikeguchi M, Nakamura S, Shimizu K, J. Chem. Phys., 110(6), 2971 (1999)

[26] Graziano G, Can. J. Chem., 80, 401 (2002)

[27] Graziano G, J. Chem. Phys., 129, 084506 (2008)

[28] Hirschfelder JO, Curtiss CF, Bird RB, Mayer MG, Molecular Theory of Gases and Liquids, Wiley, New York, 1954, p. 168.

[29] Graziano G, Chem. Phys. Lett., 396(4-6), 226 (2004)

[30] Zaytsev ID, Aseyev GG, Properties of Aqueous Solutions of Electrolytes, CRC Press, 1992p. 67.

[31] Kapustinskii A, Quart. Rev. Chem. Soc., 10, 283 (1956)

[32] Shannon R, Acta Crystallogr. Sect. A, 32, 751 (1976)

[33] Sorenson JM, Hura G, Glaeser RM, Head-Gordon T, J. Chem. Phys., 113(20), 9149 (2000)

[34] Hasseine A, Meniai AH, Korichi M, Desalination, 242(1-3), 264 (2009)

[35] Maemets V, Koppel I, J. Chem. Soc.-Faraday Trans., 94, 3261 (1998)

[36] Claussen W, Polglase M, J. Am. Chem. Soc., 74, 4817 (1952)

[37] Bostrom M, Ninham BW, J. Phys. Chem. B, 108(33), 12593 (2004)

[38] Battino R, Clever HL, Chem. Rev., 66, 395 (1966)

[39] Liu YH, Hou MQ, Yang GY, Han BX, J. Supercrit. Fluids, 56(2), 125 (2011)

[40] Ellis A, Am. J. Sci., 257, 217 (1959)

[41] Morrison TJ, J. Chem. Soc.-Faraday Trans., 40, 43 (1944)

[42] Gutmann V, Pure Appl. Chem., 63, 1715 (1991)

[43] Castrillon SRV, Giovambattista N, Aksay IA, Debenedetti PG, J. Phys. Chem. B, 113(5), 1438 (2009)

[44] Collins KD, Biophys. J., 72, 65 (1997)