The characterization of metal complexes in typical Kuwait atmospheric residues using both GPC coupled with ICP-MS and HT GC-AED

Joo-Il Park; Adel Al-Mutairi; Abdulazeem M.J. Marafie; Seong-Ho Yoon; Isao Mochida; Xiaoliang Ma

Journal of Industrial and Engineering Chemistry, Vol.34, 204-212, February, 2016

DOI10.1016/j.jiec.2015.11.011 Export Citation

The characterization of metal complexes in typical Kuwait atmospheric residues using both GPC coupled with ICP-MS and HT GC-AED

Joo-Il Park^†, Adel Al-Mutairi, Abdulazeem M.J. Marafie, Seong-Ho Yoon¹, Isao Mochida¹, and Xiaoliang Ma

Petroleum Research Center, Kuwait Institute for Scientific Research, P.O. Box 24885 Safat, 13109 Kuwait
¹Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Fukuoka 816-8580, Japan

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The aim of this study is to characterize the vanadium and nickel species in saturate, aromatic, resin and asphaltene fractions from typical Kuwait atmospheric residues, using GPC coupled with an ICP-MS and HT GC-AED. It was found that most of vanadium and nickel complexes were in both resin and asphaltene fractions, while there was very small amount of non-porphyrinic metal species in the aromatic fractions. The nickel complexes show higher molecular weight than that of the vanadium complexes. The porphyrin units existing in the asphaltenes linked to the larger aggregates, while in the resins associated with less aggregates.

Keywords:Atmospheric residue (AR);Gel permeation chromatography (GPC);Inductively plasma mass spectometer (ICP/MS);Atomic emission detector (AED);High temperature gas chromatography

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[Referenced By]

[1] Gary JH, Handwerk GE, Kaiser MJ, Petroleum Refining, Technology and Economics, Taylor and Francis Group, New York, NY, 2007.

[2] Caumette G, Lienemann CP, Merdrignac I, Bouyssiere B, Lobinski R, J. Anal. At. Spectrom., 24, 263 (2009)

[3] Speight JG, Handbook of Petroleum Analysis, John Wiley & Sons, New Jersey, NJ, 2002.

[4] Speight JG, The Chemistry and Technology of Petroleum, Taylor & Francis, New York, NY, 2006.

[5] Matar S, Chemistry of Petrochemical Process, Gulf Publishing Company, Huston, TX, 2000.

[6] Niccum PK, Santner CR, in: Meyers RA (Ed.), Handbook of Petroleum Refining Processes, McGraw-Hill, Texas, 2004.

[7] Hemler CL, Smith LF, in: Meyers RA (Ed.), Handbook of Petroleum Refining Processes, McGraw-Hill, Texas, 2004.

[8] Jayaraman A, Sexena RC, Prev. Control., 42, 123 (1995)

[9] Duyck C, Miekeley N, da Silveria CLP, Aucelio RQ, Campos RC, Grinberg P, Brandao GP, Spectroc. Acta Pt. B-Atom. Spectr., 62, 939 (2007)

[10] Stigter JB, de Hann HPM, Guicherit R, Dekkers CPA, Danne ML, Environ. Pollut., 107, 451 (2000)

[11] Marquez N, Ysambertt F, De La Cruz C, Anal. Chim. Acta, 395, 343 (1999)

[12] Biggs WR, Fetzer JC, Brown RJ, Reynolds JG, Liq. Fuels Technol., 3, 397 (1985)

[13] Mitchell PCH, Catal. Today, 7, 439 (1990)

[14] Merdrignac I, Espinat D, Oil Gas Sci. Technol. : Rev. IFP, 24, 2257 (2007)

[15] Purcell J, Merdrignac I, Rodgers R, Marshall A, Gauthier T, Guibard I, Energy Fuels, 24, 2257 (2010)

[16] Ferreira C, Tayakout-Fayolle M, Guibard I, Lemos F, Toulhoat H, Ribeiro FR, Fuel, 98, 218 (2012)

[17] Reynolds JG, Pet. Sci. Technol., 19, 979 (2001)

[18] Chen P, Xing Z, Liu M, Liao Z, Huang D, J. Chromatogr. A, 839, 239 (1999)

[19] Zeng YJ, Uden PC, J. High Resolut. Chromatogr., 17, 217 (1994)

[20] Hearn R, Berglund M, Ostermann M, Pusticek N, Yaylor P, Anal. Chim. Acta, 532, 55 (2005)

[21] Vale MGR, Damin ICF, Filho PJS, Welz B, Talanta, 74, 1385 (2008)

[22] Xu H, Que GH, Yu DY, Lu JR, Energy Fuels, 19(2), 517 (2005)

[23] Murgich J, Rodriguez J, Aray Y, Energy Fuels, 10(1), 68 (1996)

[24] Calemma V, Rausa R, D'Antona P, Montanari L, Energy Fuels, 12(2), 422 (1998)

[25] Peng P, Moralesizquierdo A, Hogg A, Strausz OP, Energy Fuels, 11(6), 1171 (1997)

[26] Kim T, Ryu J, Kim MJ, Kim HJ, Shul YG, Jeon Y, Park JI, Fuel, 117, 783 (2014)

[27] Kim T, Al-Mutairi A, Marafi AMJ, Park JI, Yoon SH, Mochida I, Fuel Process. Technol., 126, 497 (2014)

[28] Loeber L, Muller G, Morel J, Sutton O, Fuel, 77(13), 1443 (1998)

[29] Pfeiffer JP, Saal RNJ, J. Phys. Chem., 44, 139 (1940)

[30] Desprez A, Bouyssiere B, Arnaudguilhem C, Krier G, Vernex-Loset L, Giusti P, Energy Fuels, 28(6), 3730 (2014)

[31] Dechaine GP, Gray MR, Energy Fuels, 24, 2795 (2010)

[32] McKenna AM, Purcell JM, Rodgers RP, Marshall AG, Energy Fuels, 23, 2122 (2009)