Journal of Industrial and Engineering Chemistry, Vol.34, 286-291, February, 2016
Production of hydrogen-rich syngas from methane reforming by steam microwave plasma
E-mail:
Steam-methane reforming (SMR) is most commonly carried out in a catalytic reactor at temperatures from 700 to 1000 ℃. During the reforming reaction, the catalyst agglomerates under the high temperatures, showing degradation of catalytic performance with carbon deposition on the catalyst surface. Here, we report methane reforming in a steam plasma generated by microwaves at atmospheric pressure without the use of catalysts. The plasma reforming system is mainly composed of a 2.45 GHz microwave plasma torch and a plasma nozzle. Methane gas is introduced into the steam microwave plasma, which is stabilized by a swirl flow. The steam microwave plasma provides highly active species and a high-temperature plasma flame, enhancing the chemical reaction rate and eliminating the need for catalysts. We investigated the dependence of the hydrogen concentration on the steam to carbon ratio at a given plasma power. Using a specially designed plasma nozzle, we achieved high hydrogen concentrations (>70 vol.%) in the effluent streams.
- Riis T, Hagen EF, Vie JSP, Ulleberg Q, Hydrogen Production and Storage, International Energy Publications, France, 2006.
- Lipman T, An Overview of Hydrogen Production and Storage Systems with Renewable Hydrogen Case Studies, Clean Energy States Alliance, Montpeller, VT, 2011.
- O’Hayre R, Cha SW, Colella W, Prinz FB, Fuel Cell Fundamentals, John Wiley & Sons, New York, NY, 2006p. 294.
- Ogden JM, Review of Small Stationary Reformers for Hydrogen Production, Centre for Energy and Environmental Studies (CEES), Princeton, NJ, 2001.
- Qi AD, Peppley B, Karan K, Fuel Process. Technol., http://dx.doi.org/10.1016/j.fuproc.2006.05.007., 88(1), 3 (2007)
- Bromberg L, Cohn DR, Rabinovich A, Int. J. Hydrog. Energy, http://dx.doi.org/10.1016/0360-3199(95)00121-2., 22, 83 (1997)
- Lakeman JB, Browning DJ, Global status of hydrogen research, in: Defence Evaluation and Research Agency as Part of the DTI Sustainable Energy Programmes, 2001.
- Jasinski M, Dors M, Nowakowska H, Mizeraczyk J, Chem. Listy, 102, s1332 (2008)
- Sekiguchi H, Mori Y, Thin Solid Films, 435(1-2), 44 (2003)
- Jasinski M, Dors M, Mizeraczyk J, Int. J. Plasma Environ. Sci. Technol., 2, 134 (2008)
- Yoon SJ, Lee JG, Int. J. Hydrog. Energy, 37(22), 17093 (2012)
- Uhm HS, Na YH, Hong YC, Shin DH, Cho CH, Int. J. Hydrog. Energy, 39(9), 4351 (2014)
- Hong YC, Uhm HS, Phys. Plasmas, http://dx.doi.org/10.1063/, 13, 113501 (2006)
- Uhm HS, Kim JH, Hong YC, Appl. Phys. Lett., http://dx.doi.org/10.1063/1.2742782., 90, 211502 (2007)
- Gaydon AG, Proc. R. Soc. London, Ser. A, 181, 197 (1942)
- Badger RM, Bauer SH, J. Chem. Phys., 4, 711 (1936)
- Chibane L, Djellouli B, Int. J. Chem. Eng. Appl., 2, 147 (2011)