화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.33, No.3, 806-811, March, 2016
DOI10.1007/s11814-015-0238-0  Export Citation
Dehydration of D-xylose over SiO2-Al2O3 catalyst:Perspective on the pathways for condensed products
Su Jin You1, Eun Duck Park1, 2, and Myung-June Park1, 2, †
  • 1Department of Energy Systems Research, Ajou University, Suwon 16499, Korea
  • 2Department of Chemical Engineering, Ajou University, Suwon 16499, Korea
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This work addresses the kinetic mechanism for the dehydration of D-xylose over the SiO2-Al2O3 solid catalyst, where the formation of condensed products is included in addition to the production of furfural and its decomposition. The kinetic modeling and parametric sensitivity show that the isomerization of D-xylose takes place in the early stages of the reaction, followed by the dehydration of isomers. Accordingly, the homogeneous polymerization of isomers is found to be dominant. The developed model is used to evaluate the effects of operating conditions on the catalytic performance; high temperature and D-xylose concentration guarantee high furfural yield.
Keywords:D-Xylose;Furfural;Dehydration;Silica-alumina;Kinetic Modeling
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