In this study, we have developed a multi-site kinetic model that describes the sulfur poisoning and gradual sulfur removal over Cu/SSZ-13 used for NH3-SCR. Sulfur poisoning was conducted under SCR conditions and thereafter, repeated SCR experiments were conducted to examine the effect of such poisoning and the subsequent gradual removal of sulfur. In addition, the effect of sulfur poisoning was examined on NH3 TPD and ammonia oxidation experiments. The following sites were used in the kinetic model: copper in the six-membered rings as described by S1(Cu), copper in the larger cages with S2 and S3 as a site where physisorbed ammonia can attach. Further, ammonia was also adsorbed on the Bronsted sites, represented by S1(Bron) in the model, but in order not to further complicate the model, small amounts of ammonia storage on Bronsted sites were also lumped into S2. In the model, SO2 was adsorbed on the sites containing copper, which are S1(Cu) and S2. It should be noted that S1(Cu) and S2 represents hydrated copper sites. Interestingly, we observed experimentally that ammonia storage was larger after sulfur poisoning compared to before, which is why we added ammonia storage and desorption to the S1(Cu)-SO2 and S2-SO2 sites. However, ammonia was already adsorbing on the copper site; thus, these steps did not result in increased storage. Consequently, reaction steps were added where additional aminonia was adsorbed to form S1(Cu)-SO2-(NH3)(2) and S2-SO2-(NH3)(2) species, which could be interpreted as precursors to ammonium sulfates. Another aspect that must be addressed in the model is the observation in the literature that SO2 is more easily desorbed in SO2 + NH3 + O-2 TPD than SO2 + O-2 TPD. Reversible reaction steps were therefore added whereby the S1(Cu)-SO2-NH3 and S2-SO2-NH3 species were decomposed to form SO2. A final reaction step was incorporated into the model to describe the SCR reaction with ammonia attached to the sulfur sites. The developed model could well describe the sulfur poisoning and gradual regeneration during repeated SCR experiments. In addition, the model well described the NH3 TPD and NH3 oxidation before and after sulfur poisoning. (C) 2015 Elsevier B.V. All rights reserved.