Thermically treated graphene oxides (TT-GOs) are synthesized at different temperatures, 100 degrees C, 150 degrees C, 200 degrees C and 300 degrees C in a reducing environment (20% H-2/He) and investigated as electrode materials for vanadium redox flow battery (VRFB) applications. The treated graphene oxide-based electrodes are prepared by the wet impregnation method using carbon felt (CF) as support. The main aim is to achieve a suitable distribution of the dispersed graphene oxides on the CF surface in order to investigate the electrocatalytic activity for the VO2+/VO2+ and V2+/V3+ redox reactions in the perspective of a feasible large area electrodes scale-up for battery configuration of practical interest. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are carried out in a three electrode half-cell to characterize the electrochemical properties of the TT-GO-based electrodes. Physico-chemical characterizations are carried out to corroborate the electrochemical results. The TT-GO sample treated at 100 degrees C (TT-GO-100) shows the highest electrocatalytic activity in terms of peak to peak separation (Delta E = 0.03 V) and current density intensity (similar to 0.24 A cm(-2) at 30 mV/s) both toward the VO2+/VO2+ and V2+/V3+ redox reactions. This result is correlated to the presence of hydroxyl (-OH) and carboxyl (-COOH) species that act as active sites. A valid candidate is individuated as effective anode and cathode electrode in the perspective of electrodes scale-up for battery configuration of practical interest. (C) 2015 Elsevier Ltd. All rights reserved.