We quantify carbon (CO2) savings in the demand side response (DSR) programmes. We consider Short Term Operating Reserve (STOR), Triad, Fast Reserve and Smart Meter roll-out, with various types of smart interventions involved (using diesel generators, hydro-pumped generation and use of tariffs). We model CO2 emissions in each of the DSR programmes with appropriate configurations and assumptions used in the energy industry. This enables us to compare carbon emissions between the business-as-usual (BAU) solutions and the smart intervention applied, thus deriving the carbon savings. Whether such DSR produces positive CO2 savings or not depends on the used technologies, as well as the scale of the interventions, which we illustrate in examples. Crown Copyright (C) 2015 Published by Elsevier Ltd. All rights reserved.