A close-packed hexagonal (HCP)-cobalt superstructure was synthesized on a large scale through a simple, yet low-cost liquid reduction method. The cobalt superstructure was assembled by nanoflakes with strong shape anisotropy. The permittivity (epsilon(r) = epsilon' - j epsilon '') and permeability (mu(r) = mu' - j mu '') of cobalt superstructure were also studied as a function of frequency in microwave range of 1-18 GHz. It is demonstrated that permittivity displays remarkable multiple dielectric resonance peaks. Multiple magnetic resonances were also exhibited for permeability, which were discussed based on the LLG equation and exchange resonance mode. Multiple dielectric and magnetic resonances were beneficial to widen microwave absorption bandwidth. The calculated reflection loss (RL) indicated that the cobalt superstructure had potential application as a promising candidate for microwave absorption. The reflection loss was attributed to two main reasons, one is the destructive interference, which was related to the thickness of the absorbent layer, and the other one was multiple microwave reflection due to the structure assembled by nanoflakes. (C) 2015 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.