The interface between the organic and magnetic electrodes is a fundamental problem in organic spintronics devices. Therefore, bilayer structure of Alq(3)/FeCo was fabricated in a dual ultra high vacuum chamber. The electronic structure of Alq(3)-FeCo interface has been studied by X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy with Argon ion etching technique. It was found that organic layer reacts partially with the FeCo film, forming complex binding of metallic carbide and/or oxidation state in the interfacial region. Electronic injection barrier is 0.76 eV in the interface. The structural variation of the contact region is proposed to be one of the possible factors resulting in spin-injection failure. The magnetic properties of FeCo film with different thicknesses on glass substrate and Alq(3) layer are also investigated. The induced uniaxial anisotropy only presents in 3 nm FeCo thickness for glass/FeCo, while it appears in 3-5 nm FeCo for Alq(3)/FeCo. (C) 2015 Elsevier B.V. All rights reserved.