화학공학소재연구정보센터
Applied Surface Science, Vol.360, 772-776, 2016
Kinetic-limited etching of magnesium doping nitrogen polar GaN in potassium hydroxide solution
KOH based wet etchings were performed on both undoped and Mg-doped N-polar GaN films grown by metal-organic chemical vapor deposition. It is found that the etching rate for Mg-doped N-polar GaN gets slow obviously compared with undoped N-polar GaN. X-ray photoelectron spectroscopy analysis proved that Mg oxide formed on N-polar GaN surface is insoluble in KOH solution so that kinetic-limited etching occurs as the etching process goes on. The etching process model of Mg-doped N-polar GaN in KOH solution is tentatively purposed using a simplified ideal atomic configuration. Raman spectroscopy analysis reveals that Mg doping can induce tensile strain in N-polar GaN films. Meanwhile, p-type N-polar GaN film with a hole concentration of 2.4 x 10(17) cm(-3) was obtained by optimizing bis-cyclopentadienyl magnesium flow rates. (C) 2015 Elsevier B.V. All rights reserved.