In this paper, Ni-Mo alloy coatings were deposited from bath containing sodium citrate, nickel sulphate, and sodium molybdate. Essentially, this work is divided into two mains parts: (i) the optimization on the coatings deposition parameters and (ii) the effect of the heat treatment. Polarization curves and electrochemical impedance spectroscopy were acquired using potentiostat/galvanostat and a frequency response analyzer, respectively. Morphology and chemical composition of the coatings were investigated by scanning electron microscopy and energy dispersive spectroscopy, respectively. Polarization curves at different condition revealed that electroplating at temperature 40 degrees C, pH 9 provides a dense coating with high efficiency. Following the optimization of the deposition parameters, the coatings were annealed at 200, 400, and 600 degrees C for 25 min. The results showed that the coatings obtained at temperature 40 degrees C, pH9, and annealing at 600 degrees C has the highest corrosion resistance and microhardness. (C) 2015 Elsevier B.V. All rights reserved.