Novel hydrophilic polyphenylsulfone (PPSU) nanofibrous membrane was prepared by electrospinning of the PPSU solution blended with polyethylene glycol 400 (PEG 400). The influence of the PEG concentration on the membrane characteristics was studied using scanning electron microscopy (SEM), water contact angle measurement, and tensile test. Filtration performance of the membranes was investigated by measurement of pure water flux (PWF) and determination of the rejection values of the pollution indices during treatment of canned beans production wastewater. According to the results, blending the PPSU solution with 10 wt.% PEG 400 resulted in formation of a nanofibrous membrane with high porosity and increased mechanical strength which exhibited a low water contact angle of 8.9 and high water flux of 7920L/m(2)h. Flux recovery of the mentioned membrane which was assessed by filtration of a solution containing bovine serum albumin (BSA) was 83% indicating a noticeable antifouling property. (C) 2015 Elsevier B.V. All rights reserved.