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Catalysis Today, Vol.257, 318-321, 2015
Biomass to value added chemicals: Isomerisation of beta-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids
The isomerisation of p-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of p-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%. (C) 2014 Elsevier B.V. All rights reserved.