Nanoporous graphitic carbon nitride (npg-C3N4) shows much higher photocatalytic activities than bulk g-C3N4. Npg-C3N4 was used to couple with CdS quantum dots (QDs) by a simple deposition method to further increase the photocatalytic activities of the photocatalyst. The obtained photocatalyst was characterized by XRD, FT-IR, and XPS techniques; nitrogen adsorption isotherms, SEM and TEM images; and UV-vis DRS and Photoluminescence spectra. Results showed that the CdS QDs had been successfully deposited onto the surface of npg-C3N4 with a good dispersion, and the two components formed stable composites because the CdS QDs can be anchored by the rolled and curled edges of npg-C3N4. The as prepared CdS QDs/npg-C3N4 composites not only exhibited extended optical absorptions of visible light (up to 600 nm) and enhanced photocatalytic activity for the photodegradation of Rhodamine B than each of the components, but also showed good catalytic stability. (C) 2015 Elsevier B.V. All rights reserved.