We present a simple approach for preparing mesoporous carbon membranes on macroporous fly-ash-based ceramic supports via sol-gel polymerization of resorcinol with formaldehyde. The support was dip-coated and dried at 45 degrees C under ambient pressure without a special drying process. The mesoporous carbon membrane was obtained after carbonization under a nitrogen atmosphere. The coating-pyrolysis process only required one cycle. The graphitization degree increased with carbonization temperature, as shown by X-ray diffraction. However, Raman spectroscopy revealed that defects emerged at high carbonization temperature. Scanning electron microscopy clearly showed the mesoporous carbon layer and macroporous support, a uniform carbon layer with thickness less than 1 mm forming on the support. The obtained carbon membrane shows uniform pores and high mesopore volume. The flux of pure water through the mesoporous carbon membrane was as high as 167L . m(-2) . h(-1) . bar(-1). The molecular weight cutoff of this membrane was found to be about 20,000 Da.