Chemical Engineering Journal, Vol.278, 527-532, 2015
A novel condensation reactor for efficient CO2 to methanol conversion for storage of renewable electric energy
A novel reactor design for the conversion of CO2 and H-2 to methanol is developed. The conversion limitations because of thermodynamic equilibrium are bypassed via in situ condensation of a water/methanol mixture. Two temperatures zones inside the reactor ensure optimal catalyst activity (high temperature) and full conversion by condensation at a lower temperature in a separate zone. Due to this full gas conversion there is no need for an external recycle of reactants. Experimental work confirmed full carbon conversion (>99.5%) and high methanol selectivity (>99.5% on carbon basis). Additionally, it was shown that due the temperature gradient inside the reactor significant reaction rates are achieved under natural convection conditions. (C) 2014 Elsevier B.V. All rights reserved.
Keywords:CO2 hydrogenation;Methanol synthesis;Product condensation;Energy storage;Natural convection;Process intensification