화학공학소재연구정보센터
Chemical Engineering Journal, Vol.278, 527-532, 2015
A novel condensation reactor for efficient CO2 to methanol conversion for storage of renewable electric energy
A novel reactor design for the conversion of CO2 and H-2 to methanol is developed. The conversion limitations because of thermodynamic equilibrium are bypassed via in situ condensation of a water/methanol mixture. Two temperatures zones inside the reactor ensure optimal catalyst activity (high temperature) and full conversion by condensation at a lower temperature in a separate zone. Due to this full gas conversion there is no need for an external recycle of reactants. Experimental work confirmed full carbon conversion (>99.5%) and high methanol selectivity (>99.5% on carbon basis). Additionally, it was shown that due the temperature gradient inside the reactor significant reaction rates are achieved under natural convection conditions. (C) 2014 Elsevier B.V. All rights reserved.