The methanation of CO2 was investigated over a wide range of partial pressures of products and reactants using a gradientless, spinning-basket reactor operated in batch mode. The rate and selectivity of CO2 methanation, using a 12 wt% Ni/gamma-A1203 catalyst, were explored at temperatures 453-483 K and pressures up to 20 bar. The rate was found to increase with increasing partial pressures of H-2 and CO2 when the partial pressures of these reactants were low; however, the rate of reaction was found to be insensitive to changes in the partial pressures of H-2 and CO2 when their partial pressures were high. A convenient method of determining the effect of H2O on the rate of reaction was also developed using the batch reactor and the inhibitory effect of H2O on CO2 methanation was quantified. The kinetic measurements were compared with a mathematical model of the reactor, in which different kinetic expressions were explored. The kinetics of the reaction were found to be consistent with a mechanism in which adsorbed CO2 dissociated to adsorbed CO and O on the surface of the catalyst with the rate limiting step being the subsequent dissociation of adsorbed CO. (C) 2015 Elsevier Ltd. All rights reserved.