Chemical Physics Letters, Vol.626, 96-101, 2015
Ripening kinetics of laser-generated plasmonic nanoparticles in different solvents
Pulsed laser ablation in liquid is considered to be a fast nanoparticle-synthesis method taking place on ps to mu s timescale. Here, we report the comparably slow ripening kinetics of laser-generated plasmonic nanoparticles (copper, silver, and gold) immediately after ablation. The growth dynamics is studied in situ by following the surface plasmon resonance and correlated to known models. We thereby identify a two-step diffusion-controlled coalescence and growth mechanism, quantify their kinetic constants and show the effect of different solvents (water, acetone, ethanol, and ethyl acetate). (C) 2015 Published by Elsevier B.V.