The energy-conserving performance of dividing wall column (DWC) is discussed in this paper. The heat transfer through the dividing wall is considered and the results are compared with that of common heat insulation dividing wall column (HIDWC). Based on the thermodynamic analysis of heat transfer dividing wall column (HTDWC) and HIDWC, both computer simulation and experiments are employed to analyze the energy-conserving situation. Mixtures of n-hexane, n-heptane and n-octane are chosen as the example for separation. The results show that the energy consumption of HTDWC is 50.3% less than that of conventional distillation column, while it is 46.4% less than that of HIDWC. It indicates that DWC is efficient on separating three-component mixtures and HTDWC can save more energy than HIDWC. Thus it is necessary to consider the heat transfer while applying DWC to industry. (C) 2015 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.