Noble metal network nanostructures with three-dimensionally (3D) interconnected architectures are attracting much attention because of their unique catalytic, electrical, and optical properties. In this work, we report a facile ethylenediaminetetraacetic acid (EDTA) mediated chemical reduction route for the synthesis of high-quality palladium (Pd) nanowire networks (Pd-NWNWs). During the synthesis, EDTA interacts with PdCl2 to generate EDTA-Pd-II complex, which efficiently decreases the reduction potential of Pd-II precursor. The slow reduction rate is crucial for the generation of Pd nanowires. The morphology, composition, and structure of Pd-NWNWs are fully investigated by various physical characterizations. The electrocatalytic activity of Pd-NWNWs for the hydrazine oxidation reaction (HOR) is also studied by cyclic voltammetry, electrochemical impedance spectroscopy, and chronoamperometry, etc. Compared to commercial Pd black, Pd-NWNWs exhibit remarkably improved electrocatalytic activity and stability for the HOR. (C) 2015 Elsevier Ltd. All rights reserved.