Electrochimica Acta, Vol.164, 182-186, 2015
Platinum Nanowires: Structural and catalytic evolution upon annealing temperature
Platinum nanowires (NWs) were prepared by electrodeposition in porous anodic aluminum oxide (AAO) template and then annealed at 200 degrees C, 400 degrees C and 600 degrees C, respectively. Compared to the commercial carbon-supported Pt catalysts, all Pt NWs exhibited better electrocatalytic activities towards both methanol oxidation reaction (MOR) and oxygen reduction reaction (ORR). The MOR activity of the Pt NWs increased dramatically as the annealing temperature (T-A) increased, whereas the ORR activity followed the trend of 'as-prepared' > 600 degrees C > 400 degrees C > 200 degrees C. This phenomenon should be attributed to the NWs surface rearrangement during the annealing process. (C) 2015 Elsevier Ltd. All rights reserved.