Nanoencapsulation of n-octadecane phase change material with silica shell was performed through interfacial hydrolysis and polycondensation of tetraethyl orthosilicate in miniemulsion. The chemical composition and crystallinity of the synthesized n-octadecane@SiO2 nanocapsules were characterized by FT-IR spectroscopy and XRD analysis. DSC (differential scanning calorimetry) and TG results demonstrated that the as-prepared nanocapsules have high heat storage capability and good thermal stability. The melting enthalpy and encapsulation ratio of the nanocapsules were as high as 109.5 J g(-1) and 51.5%, respectively. Most importantly, n-octadecane@SiO2 nanocapsules with different morphologies and sizes (169-563 nm) have been conveniently obtained via tuning water-to-ethanol ratio in continuous phase of the miniemulsion. With decreasing size of the n-octadecane@SiO2 nanocapsules, the phase change temperatures move to lower values due to Gibbs-Thomson effect. Moreover, the as-prepared nanocapsules possess high thermal conductivity, and can maintain their phase transition properties perfectly after 500 melting-solidifying thermal cycles, making them ideal candidates as thermal energy storage materials. (C) 2015 Elsevier Ltd. All rights reserved.