In this study, the performance of a novel photovoltaic/thermal (PV/T) air dual-heat-source composite heat pump hot water system was investigated experimentally and analyzed theoretically. First, a system that simulates a solar PV/T collector by electric heating was built and tested to validate the superiority of the hot water system. The system was divided into dual-heat-source operating mode and single-heat-source operating mode. Results showed that the average COP and COPsys for dual-heat-source operating mode were 2.49 and 2.24, respectively, and for single-heat-source operating mode were 1.40 and 1.31, respectively, which indicate that the former had better system performance. Then, the actual PV/T collector was used in the system. The results showed that the average electrical gain and heat gain were 278W and 664W, respectively. The average electrical efficiency and heat efficiency were 14.5% and 36.02%, respectively. Meanwhile, the comprehensive efficiency was more than 50%. The average COP and COPsys of the heat pump were 4.08 and 3.07, respectively, along with the system exergy efficiency of 0.33. Therefore, the PV/T air dual-heat-source composite heat pump hot water system has excellent performance and is worth promoting and applying. (C) 2015 Elsevier B.V. All rights reserved.