Energy Conversion and Management, Vol.98, 314-321, 2015
Stearic-acid/carbon-nanotube composites with tailored shape-stabilized phase transitions and light-heat conversion for thermal energy storage
The development of functional materials with both light-heat conversion and thermal energy storage properties is of crucial importance for efficient utilization of sunlight to meet the growing demand for sustainable energy. In this work, the shape-stabilized phase change composites were designed and prepared by integration of stearic acid (SA) and acid-treated carbon nanotubes (a-CNTs). The a-CNTs not only acted as a flexible matrix but also endowed the composites high light-heat conversion ability. The reversible phase transitions shifted from high temperatures (T-m = 74 degrees C, T-f = 57 degrees C) of pure SA to near room temperature (T-m = similar to 30 degrees C, Tf = similar to 22 degrees C) of SA/a-CNTs composites, probably resulting from the strong interface confinement effect. The phase change enthalpy of the SA/a-CNTs composite could also be tailored by changing the mass ratio of SA and a-CNTs. The composites containing SA of 54.2 wa, 67.8 wt.% and 79.5 wt.% presented the melting enthalpy of 76.3 J/g, 98.8 J/g and 111.8 J/g, respectively. Moreover, the phase transition of SA/a-CNTs composite could be driven by sunlight for the energy storage/release. Therefore, this research provides a new platform for improving solar utilization, and understanding the phase transition behaviors of organic PCMs in dimensionally confined environments as well. (C) 2015 Elsevier Ltd. All rights reserved.
Keywords:Phase change material;Carbon nanotube;Nanocomposite;Light-heat conversion;Thermal energy storage