Carbon dioxide was photocatalytically reduced to produce methanol and ethanol in the presence of CuO-loaded titania powders suspended in water containing Na2SO3 as the hole scavenger. The photocatalysts were synthesized by an impregnation method using P25 (Degussa) as support. At the optimum amount of copper oxide loading (3 wt%), the methanol and ethanol yields were 12.5 and 27.1 mu mol/g-catal., respectively, following 6 h of UV illumination. The redistribution of photogenerated charge carriers in CuO/TiO2 facilitates electron trapping and prohibits the recombination of electrons and holes, which significantly increases photoefficiency. The addition of Na2SO3 promotes the formation of ethanol.