화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.54, No.48, 12165-12176, 2015
An Experimental and Modeling Study of the Adsorption Equilibrium and Dynamics of Water Vapor on Activated Carbon
In this work, the adsorption of water vapor on a commercial activated carbon is studied by means of static and dynamic measurements. To this end, two customized setups are used, which are able to deal with the challenges associated with adsorption measurements under humid conditions. In the first part, the equilibrium of water vapor on activated carbon during adsorption and desorption at 45 degrees C is characterized. The equilibrium adsorbed amount of water vapor exhibits a pronounced hysteresis loop, requiring the use of an isotherm model with hysteresis to describe the data. In the second part, fixed-bed experiments for both adsorption and desorption conditions at three feed velocities are presented. These dynamic experiments are described by a nonisothermal detailed column model, which considers the linear driving force model for mass transfer and axial dispersion. Heat and mass transfer coefficients are estimated so as to describe the fixed-bed experiments. The results from the static and dynamic measurements are shown to be consistent with each other for both adsorption and desorption conditions, provided the hysteretic behavior of the adsorption equilibrium is considered. Finally, it is shown that the use of an average value for the mass transfer coefficient results in good agreement between experiment and simulation, and the improvement due to a more complex model is minimal.