Inorganic Chemistry, Vol.54, No.18, 8872-8874, 2015
Dynamic Entangled Framework Based on an Iridium-Organic Unit Showing Reversible Luminescence Turn-On Sensing
A new entangled metal organic framework shows reversible structural dynamics and luminescence changing in response to the loss of guest H2O molecules. Furthermore, an intense and sensitive luminescence turn-on sensing was observed by the naked eye for 1 upon detection of the volatile organic solvent molecule CH3CN, accompanied by reversible structural transformation.