The application of a polyaromatic acid-base blend membrane from partially fluorinated and sulfonated aromatic polyether and the polybenzimidazole F6PBI has been investigated for hydrogen production using SO2 electrolysis. Several membrane electrode assembly (MEA) pre-doping strategies have been investigated using polarisation curves. Membrane thickness variation, voltage cycling and long term operation at constant current (0.1 A cm(-2)) was also performed. Scanning electron microscopy (SEM) and TGA-MS was used to evaluate MEA stability before and after long term operation. It was found that doping the MEA after hot pressing performs the best reaching a current density of 0.3 A cm(-2). The performance could also be improved by cycling the voltage 16 times to reach 0.33 A cm(-2). Long term operation showed stable voltage at 0.1 A cm(-2) staying below 0.8 V. SEM images showed that no significant sulfur deposition was present while TGA-MA analysis confirmed some degradation after the 140 h of operation. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.