Journal of Chemical and Engineering Data, Vol.60, No.12, 3483-3495, 2015
Apparatus To Measure the Vapor Pressure of Slowly Decomposing Compounds from 1 Pa to 10(5) Pa
This article describes an apparatus and method for measuring vapor pressures in the range from 1 Pa to 10(5) Pa. Its three distinctive elements are (1) the static pressure measurements were made with only a small temperature difference between the vapor and the condensed phase, (2) the sample was degassed in situ, and (3) the temperature range extended up to 200 degrees C. The apparatus was designed to measure metal organic precursors, which often are toxic, pyrophoric, or unstable. Vapor pressures are presented for naphthalene, ferrocene, diethyl phthalate, and TEMAH (tetrakisethylmethylaminohafnium). Also presented are data for the temperature-dependent decomposition rate of TEMAH.