화학공학소재연구정보센터
Journal of Materials Science, Vol.32, No.14, 3667-3674, 1997
Growth Crystallography of Bi12SiO20 Single-Crystals Solidified by a Floating-Zone Method
Relations between the growth directions of Bi12SiO20 (BSO) single-crystal rods solidified by a floating zone method and the pulling parameters were studied using an X-ray back-reflection Laue technique. It was found that when a platinum wire is used as a seed, the growth direction of the produced BSO single-crystal rod is related to the pulling rate. Statistically, the probability of the growth direction approaching [011], [112] or [001] appears to increase in this order with increase of the pulling rate. In addition when a BSO crystal is used as a seed, the growth direction of the produced BSO crystal rod has the same orientation as the seed crystal if the pulling rate is less than 30 mm h(-1). If the pulling rate is higher than 30 mm h(-1), the growth appears to incline mostly to [112] if the seed orientation is near [011] or [111] but far from [001], or to [001] if the seed orientation is near [001] but far from both [011] and [111]. The angle of inclination increases with the pulling rate, and also with the difference in angle between the orientation of seed crystal and [112] or [001]. The facet morphology of the BSO single-crystal rod is related to its growth direction. The cross-section of the BSO single-crystal rod grown along [001] is an octagon with tetrad-rotational symmetry, that grown along [001] is an ellipsoid with diad-rotational symmetry, and that along [111] is a hexagon with triad-rotational symmetry. The cross-sections of the BSO single-crystal rods grown in other directions are not regular, because there is no clear symmetry.